Abstract
The crystal and molecular structure of the complex [Co(S2CNC4H8O)3]·CH3CN has been determined by X-ray crystallography. The compound crystallizes in the triclinic system, space group P\overline 1 , with lattice parameters a = 10.561(2), b = 11.114(2), c = 13.011(3) Å, α = 103.88(3), β = 101.58(3), γ = 114.91(1)°, and Z = 2. X-ray analysis reveals that the cobalt(III) atom is located at the apparent intersection of D 3 symmetry. Despite the apparent presence of the rotational axes, all of the atoms in the structure were found to be unique; there are no symmetry-related atoms. The central cobalt atom is octahedrally coordinated by an arrangement of six S atoms. The octahedron is distorted as a result of the forced configuration of the four-membered chelate ring. The average Co–S distance is 2.273 Å. The FT-IR spectra clearly show there are acetonitrile molecules in the crystal lattice.
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Thorn, G.D.; Ludwig, R.A. The Dithiocarbamates and Related Compounds; Elsevier: New York, 1962, p. 1.
Gimeno, M.C.; Jambrina, E.; Laguna, A.; Laguna, M.; Murray, H.H.; Terroba, R. Inorg. Chim. Acta 1996, 249, 69.
Allen, F.H.; Kennard, O. Chem. Des. Autom. News 1993, 8, 31.
Baldas, J.; Bonnyman, J. Nucl. Med. Biol. 1992, 19, 741.
Xie, J.; Funakoshi, T.; Shimada, H.; Kojima, S. Res. Commun. Mol. Pathol. Pharmacol. 1994, 86(2), 245.
Thorn, G.D.; Ludwig, R.A. The Dithiocarbamates and Related Compounds; Elsevier: Amsterdam, 1962.
Riekkola, M.L.; Pakkanen, T.; Niinisto, L. Acta Chemica Scand. 1983, A37, 807.
Sakla, A.B.; Helmy, A.A.; Beyer, W.; Harhash, F.E. Talanta. 1979, 26, 519.
Kumar, R.; Singh, N.; Singh, H. J. Indian Chem. Soc. 1979, 56, 838.
Singh, N.; Kumar, R.; Kansal, B.D. Chromatographia 1978, 11, 408.
Gahan, L.R.; Hughes, J.G.; O'Connor, M.J.; Oliver, P.J. J. Inorg. Chem. 1979, 18, 933.
O'Connor, C.; Gilbert, J.D.; Wilkinson, G. J. Chem. Soc. (A) 1969, 84.
Sheldrick, G.M. SADABS, Program for Empirical Absorption Correction of Area Dotector Data, University of Gottingen: Germany, 1996.
Sheldrick, G.M. SHELXTL, Version 5 Reference Manual; Siemens Analytical X-ray Sysytems: Madison, WI, 1996.
Wilson, A.J.C. International Table for X-ray Crystallography; Kluwer Academic Pulishers: Dordrecht, 1992; Vol. C, Tables 6.1.1.4 (pp. 500-502) and 4.2.6.8 (pp. 219-222) respectively.
Brennan, T.; Bernal, I. J. Phys. Chem. 1968, 73, 433.
Healy, P.C.; Connor, J.W.; Skelton, B.W.; White, A.H. Aust. J. Chem. 1990, 43, 1083.
Ricci, J.S., Jr.; Eggars, C.A.; Bernal, I. Inorg. Chim. Acta 1972, 6, 97.
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Zhang, J., Jian, F., Lu, L. et al. Structure and characterization of tris(4-morpholinedithiocarbamato-S,S′)cobalt(·)acetonitrile solvate complex: [Co(S2CNC4H8O)3]·CH3CN. Journal of Chemical Crystallography 31, 251–254 (2001). https://doi.org/10.1023/A:1014318410461
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DOI: https://doi.org/10.1023/A:1014318410461