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New Complexes of Mn(II), Co(II), Ni(II), Cu(II), Zn(II) and Cd(II) with 3,3-dimethylglutaric Acid

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Abstract

Conditions for the preparation of Mn(II), Co(II), Ni(II), Cu(II), Zn(II) and Cd(II)3,3-dimethylglutarates were investigated and their quantitative composition, solubility in water at 293 K and magnetic moments were determined. IR spectra and powder diffraction patterns of the complexes prepared with general formula MC7H10O4⋅nH2O (n=0−2) were recorded and their thermal decomposition in air were studied. During heating the hydrated complexes of Mn(II),Co(II), Ni(II) and Cu(II) are dehydrated in one step and next all the anhydrous complexes decompose to oxides directly (Mn, Co, Zn) or with intermediate formation free metal (Ni,Cu) or oxocarbonates (Cd). The carboxylate groups in the complexes studied are bidentate. The magnetic moments for the paramagnetic complexes of Mn(II), Co(II), Ni(II) and Cu(II)attain values 5.62, 5.25, 2.91 and 1.41 M.B., respectively.

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References

  1. F. Beilstein, Handbuch der organischen Chemie, Bd 2, Springer Verlag, Berlin 1930, p. 684.

    Google Scholar 

  2. A. B. Charette and H. Juteau, Tetrahedron, 53 (1997) 1627.

    Article  Google Scholar 

  3. E. C. Amaral and R. A. Guedes de Carvalho, J. Inorg. Chem., 31 (1969) 269.

    Google Scholar 

  4. W. Brzyska and W. Ożga, Polish J. Chem., 75 (2001) 43.

    CAS  Google Scholar 

  5. S. F. A. Kettle, Physical Inorganic Chemistry, Oxford University Press, 1996.

  6. K. Burger, Coordination Chemistry. Experimental Methods. Akadémiai Kiadó, Budapest 1973.

    Google Scholar 

  7. W. Brzyska, W. Wołodkiewicz, Z. Rzączyńska and T. Głowiak, Monatsh., 126 (1995) 225.

    Google Scholar 

  8. T. Kavata, S. Ochaba, T. Tokii, Y. Muto and M. Koto, Acta Crystal., C, 48 (1992) 1590.

    Article  Google Scholar 

  9. W. Clegg, D. R. Harbon, P. A. Hunt, I. N. Little and B. P. Straugham, Acta Crystal., C, 46 (1990) 750.

    Article  Google Scholar 

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Authors and Affiliations

  1. Department of General Chemistry, Faculty of Chemistry, Maria Curie Skłodowska University, PL 20031, Lublin, Poland

    W. Brzyska & W. Ożga

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  1. W. Brzyska
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  2. W. Ożga
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Brzyska, W., Ożga, W. New Complexes of Mn(II), Co(II), Ni(II), Cu(II), Zn(II) and Cd(II) with 3,3-dimethylglutaric Acid. Journal of Thermal Analysis and Calorimetry 67, 623–629 (2002). https://doi.org/10.1023/A:1014300720524

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