Abstract
The main mechanisms of radiation embrittlement of reactor vessel materials are considered to be hardening of material as a result of the formation of matrix defects, for example, micropores and second-phase precipitates – copper and others, and a change in the cohesive strength of grain boundaries as a result of the segregation of surface-active impurities, primarily, phosphorus. The question of the degree to which the latter mechanism affects the change in the properties of reactor-vessel materials under irradiation remains open. In the present paper, computational estimates of the kinetics of radiation-stimulated segregation of phosphorus on grain boundaries in reactor-vessel materials and the resulting changes in the mechanical characteristics of steel are compared with corresponding experimental data.
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Nikolaeva, A.V., Nikolaev, Y.A., Kevorkyan, Y.R. et al. Influence of Radiation-Stimulated Grain-Boundary Segregation of Phosphorus on the Operational Properties of Nuclear-Reactor-Vessel Materials. Atomic Energy 91, 884–895 (2001). https://doi.org/10.1023/A:1014257605632
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DOI: https://doi.org/10.1023/A:1014257605632