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Activity of the Components of Binary Alloys of Alkali Metals: Na–K System

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Abstract

The activity coefficients of the components of the Na–K binary system are determined proceeding from the thermodynamic conditions of liquid–vapor equilibrium. The obtained data are in satisfactory agreement with the results of calculation of these activity coefficients by the pattern of the liquidus curve and using integral heats of mixtures of sodium–potassium alloys, as well as with the experimental data obtained by the emf method and by the effusion method.

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REFERENCES

  1. Shpil'rain, E.E. and Kessel'man, P.M., Osnovy teorii teplofizicheskikh svoistv veshchestv (Fundamentals of the Theory of Thermal Properties of Materials), Moscow: Energiya, 1977.

    Google Scholar 

  2. Kagan, D.N., Shpil'rain, E.E., and Krechetova, G.A., Teplofiz. Vys. Temp., 1980, vol. 18, no. 3, p. 639.

    Google Scholar 

  3. Kagan, D.N. and Krechetova, G.A., Teplofiz. Vys. Temp., 1981, vol. 19, no. 3, p. 519.

    Google Scholar 

  4. Prigogine, I. and Defay, R., Chemical Thermodynamics, London: Longmans Green, 1954. Translated under the title Khimicheskaya termodinamika, Novosibirsk: Nauka, 1966.

    Google Scholar 

  5. Bearman, R.J., J. Chem. Phys., 1960, vol. 32, no. 5, p. 1308.

    Google Scholar 

  6. Tyrrell, H.J.V., J. Chem. Soc., 1963, no. 111, p. 1599.

  7. Lotlin, T. and McLaughlin, E., J. Phys. Chem., 1969, vol. 73, no. 1, p. 186.

    Google Scholar 

  8. Al-Chalalabi, H.A. and McLaughlin, E., Mol. Phys., 1970, vol. 19, no. 5, p. 703.

    Google Scholar 

  9. Kogan, V.G., Geterogennye ravnovesiya (Heterogeneous Equilibria), Leningrad: Khimiya, 1968.

    Google Scholar 

  10. Khar'kov, E.I., Lysov, V.I., and Fedorov, V.E., Fizika zhidkikh metallov (Physics of Liquid Metals), Kiev: Vishcha Shkola, 1979.

    Google Scholar 

  11. Shpil'rain, E.E., Belova, A.M., Shkermontov, V.I., et al., Teplofiz. Vys. Temp., 2001, vol. 39, no. 4, p. 552 (High Temp. (Engl. transl.), vol. 39, no. 4, p. 511).

    Google Scholar 

  12. Shpil'rain, E.E., Belova, A.M., Shkermontov, V.I., et al., Teplofiz. Vys. Temp., 2001, vol. 39, no. 4, p. 674 (High Temp. (Engl. transl.), vol. 39, no. 4, p. 629).

    Google Scholar 

  13. Shpil'rain, E.E., Belova, A.M., Shkermontov, V.I., et al., Teplofiz. Vys. Temp., 2001, vol. 39, no. 5, p. 724 (High Temp. (Engl. transl.), vol. 39, no. 5).

    Google Scholar 

  14. Semenov, A.M., Dokl. Akad. Nauk SSSR, 1984, vol. 278, no. 4, p. 866.

    Google Scholar 

  15. Lunin, V.Yu. and Semenov, A.M., Teplofiz. Vys. Temp., 1985, vol. 23, no. 3, p. 456.

    Google Scholar 

  16. Kriger, V.A., Lunin, V.Yu., and Semenov, A.M., Teplofiz. Vys. Temp., 1986, vol. 24, no. 3, p. 474.

    Google Scholar 

  17. Shpil'rain, E.E., Yakimovich, K.A., Totskii, E.E., et al., Teplofizicheskie svoistva shchelochnykh metallov (Thermal Properties of Alkali Metals), Moscow: Izd. Standartov, 1970.

    Google Scholar 

  18. Scatchard, G. and Raymond, B.L., J. Am. Chem. Soc., 1938, vol. 60, no. 6, p. 1278.

    Google Scholar 

  19. Heer, C.V., Statistical Mechanics, Kinetic Theory, and Stochastic Processes, New York: Academic, 1972. Translated under the title Statisticheskaya mekhanika, kineticheskaya teoriya i stokhasticheskie protsessy, Moscow: Mir, 1976.

    Google Scholar 

  20. Kirillin, V.A., Sheindlin, A.E., and Shpil'rain, E.E., Termodinamika rastvorov (Thermodynamics of Solutions), Moscow: Energiya, 1980.

    Google Scholar 

  21. Fokin, L.R., Teryaev, V.V., Trelin, Yu.S., and Mozgovoi, A.G., Obz. Teplofiz. Svoistvam Veshchestv, 1983, no. 4, p. 44.

  22. Beketov, V.G., Rabinovich, V.A., and Rogovin, M.D., Raschet termodinamicheskikh svoistv vlazhnykh gazov v oblasti parametrov ot 200 do 400 K i ot 0.1 do 10 MPa. Metodika GSSD. MR 99-93/M (Calculation of Thermodynamic Properties of Humid Gases at 200-400 K and 0.1-10 MPa. GSSD Procedure. MR 99-93/M), Moscow: Izd. Standartov, 1993, p. 1.

    Google Scholar 

  23. Mulenko, I.A., Solovei, V.B., Khomkin, A.L., and Tsurkin, V.N., Teplofiz. Vys. Temp., 1999, vol. 37, no. 3, p. 518 (High Temp. (Engl. transl.), vol. 37, no. 3, p. 494).

    Google Scholar 

  24. Onishchenko, V.P., Study of Thermodynamic Properties of Liquid Alkali Metals, Cand. Sci. (Tech.) Dissertation, Odessa: Odessa Inst. of Refrigeration Engineering, 1973.

    Google Scholar 

  25. Krasnyi, Yu.P. and Onishchenko, V.P., Fiz. Zhidk. Sostoyaniya, 1976, no. 4, p. 29.

  26. Shpil'rain, E.E., Yakimovich, K.A., Skovorod'ko, S.N., and Mozgovoi, A.G., Obz. Teplofiz. Svoistvam Veshchestv, 1983, no. 6, p. 1.

  27. Mozgovoi, A.G., Novikov, I.I., Pokrasin, M.A., et al., Obz. Teplofiz. Svoistvam Veshchestv, 1985, no. 1, p. 1.

  28. Redlich, O. and Kister, A.T., Ind. Eng. Chem., 1948, vol. 40, no. 2, p. 345.

    Google Scholar 

  29. Bonnier, E. and Desre, P., C. R. Acad. Sci., Paris, 1959, vol. 249, no. 17, p. 1664.

    Google Scholar 

  30. Cafasso, F.A., Khanna, V.M., and Feder, H.M., Adv. Phys., 1967, vol. 16, no. 63, p. 535.

    Google Scholar 

  31. Lokshin, E.P. and Ignatov, O.S., Teplofiz. Vys. Temp., 1971, vol. 9, no. 1, p. 94.

    Google Scholar 

  32. Lokshin, E.P., Development of Methods to Obtain High-Purity Alkali Metals and Materials on Their Basis, Doctoral (Tech.) Dissertation, Moscow: GIREDMET, 1998.

    Google Scholar 

  33. Lantratov, M.F., Zh. Prikl. Khim., 1973, vol. 46, no. 7, p. 1485.

    Google Scholar 

  34. Kagan, D.N. and Krechetova, G.A., Teplofiz. Vys. Temp., 1981, vol. 19, no. 3, p. 519.

    Google Scholar 

  35. Kagan, D.N., Teplofiz. Vys. Temp., 1988, vol. 26, no. 3, p. 478.

    Google Scholar 

  36. Kagan, D.N., Krechetova, G.A., and Shpil'rain, E.E., Teplofiz. Vys. Temp., 1999, vol. 37, no. 5, p. 716 (High Temp. (Engl. transl.), vol. 37, no. 5, p. 685).

    Google Scholar 

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Authors and Affiliations

  1. IVTAN (Institute of High Temperatures) Scientific Association, Russian Academy of Sciences, Moscow, 127412, Russia

    E. E. Shpil'rain, V. I. Shkermontov, S. N. Skovorod'ko & A. G. Mozgovoi

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  1. E. E. Shpil'rain
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  2. V. I. Shkermontov
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  3. S. N. Skovorod'ko
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  4. A. G. Mozgovoi
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Shpil'rain, E.E., Shkermontov, V.I., Skovorod'ko, S.N. et al. Activity of the Components of Binary Alloys of Alkali Metals: Na–K System. High Temperature 40, 33–43 (2002). https://doi.org/10.1023/A:1014230114968

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