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Effect of Sr Substitution on Catalytic Activity of La1-XSrxMnO3 (0≤x≤0.8) Perovskite-Type Oxides for Catalytic Decomposition of Hydrogen Peroxide

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Abstract

La1−x SrxMnO3 (0≤x≤0.8) perovskite-type oxides were synthesized by the combined EDTA-citrate complexing method and their catalytic activity for the decomposition of hydrogen peroxide was investigated. Hydrogen peroxide decomposition was observed as a first-order reaction on these catalysts. With the increase of Sr substitution, the catalytic activity increased accordingly. Through analysis of the kinetic results, the compensation effect was found for these perovskites and Mn4+ ions were ascribed as the active sites of hydrogen peroxide decomposition.

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Authors and Affiliations

  1. State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, P.O. Box 110, Dalian, 116023, China

    Huanghe Yang, Tao Zhang, Hanjing Tian, Junwang Tang, Dezhu Xu, Weishen Yang & Liwu Lin

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  1. Huanghe Yang
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  2. Tao Zhang
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  3. Hanjing Tian
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  4. Junwang Tang
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  5. Dezhu Xu
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  6. Weishen Yang
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  7. Liwu Lin
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Correspondence to Tao Zhang.

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Yang, H., Zhang, T., Tian, H. et al. Effect of Sr Substitution on Catalytic Activity of La1-XSrxMnO3 (0≤x≤0.8) Perovskite-Type Oxides for Catalytic Decomposition of Hydrogen Peroxide. Reaction Kinetics and Catalysis Letters 73, 311–316 (2001). https://doi.org/10.1023/A:1014115508872

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