Abstract
Catalysis is a science relying on many disciplines. The advent of industrial catalytic technologies in the last century has, most often, resulted from a sequential interaction between chemists and chemical engineers, both communities developing their own fundamental and applied sciences, i.e., a multidisciplinary process. Some of the major lessons learned in the past century, and related achievements, are illustrated and discussed. Challenges for catalysis research in the 21st century are identified, based on the current knowledge of catalysis researchers, recent fundamental and applied developments, and current or long-term objectives of the global chemical industry.
Similar content being viewed by others
references
H. Heinemann, Catal. Lett., 1 (1988) 413.
J. R. Rostrup-Nielsen, in Combinatorial Catalysis and High Throughput Catalyst Design and Testing, E. G. Derouane et al. (eds.); NATO ASI Science Series C, Vol. 560; Kluwer Academic Pu blishers, Dordrecht, The Netherlands, 2000, p. 337.
S. Helveg, J.V. Lauritsen, E. Laegsgaard, I. Stensgaard, J. K. Nørskov, B. S. Clausen, H. Topsøe, and F. Besenbacher, Phys. Rev. Lett., 84 (2000) 951.
C. Doornkamp and V. Ponec, J. Mol. Catal. A:Chemical, 162 (2000) 19.
M. E. Davis, Chemtech, August (1992) 498.
W. Chen, L. Xu, and J. Xiao, Tetrahedron Lett., 42 (2001) 4275; W. Chen and J. Xiao, Tetrahedron Lett., 41 (2000) 3697; W. Chen, L. Xu, and J. Xiao, Org. Lett., 2 (2000) 2675; W. Chen W and J. Xiao J, UK Patent Application GB01/00367 (2000).
R. Periana, D. J. Taube, S. Gamble, and H. Taube, Science, 259 (1993) 340.
R. Periana, D. J. Taube, S. Gamble, H. Taube, and H. Fuji, in Catalytic Activation and Functionalization of Light Alkanes, E. G. Derouane, J. Haber, F. Lemos, F. R. Ribeiro, and M. Guisnet (eds.); NATO ASI Science Series 3, Vol. 44; Kluwer Academic/Plenum Publishers, Dordrecht, The Netherlands, 1998, p. 297.
E. E. Davies and A. J. Kolombos, US Patent, 4,175,057 (1979).
C. D. Gosling, F. P. Wilcher, L. Sullivan, and R. A. Mountford, Hydrocarbon Process., December (1991) 69.
L. Wang, L. Tao, M. Xie, G. Xu, J. Huang, and Y. Xu, Catal. Lett., 21 (1993) 35.
S.B. Abd Hamid, J. R. Anderson, I. Schmidt, C. Bouchy, C. J. H. Jacobsen, and E. G. Derouane, Catal. Today, 63 (2000).
J. R. Anderson, Ph.D. Thesis, University of Liverpool, June 2001.
C. Bouchy, I. Schmidt, J. R. Anderson, C. H. J. Jacobsen, E. G. Derouane, and S. B. Abd Hamid, J. Mol. Catal. A:Chemical, 163 (2000) 283.
E. G. Derouane, S. B. Abd Hamid, I. I. Ivanova, N. Blom, and P. E. Højlund Nielsen, J. Mol. Catal., 86 (1994) 371.
I. I. Ivanova, N. Blom, and E. G. Derouane, J. Mol. Catal., 109 (1996) 327.
S. B. Abd Hamid, P. Pal, and E. G. Derouane, Catal. Today, 64 (2001) 129.
S. B. Abd Hamid, G. Centi, Pal P, and E. G. Derouane, Topics Catal., in press (2001).
P. Pal, Ph.D. research in progress, University of Liverpool, unpublished results.
T. Okuhara, N. Mizuno, and M. Misono, Adv. Catal., 41 (1996) 113.
E. G. Derouane., in A Molecular View of Heterogeneous Catalysis, E. G. Derouane (ed.), De Boeck Université, Bruxelles, 1998, pp. 5-27.
E. G. Derouane, J. M. André, and A. A. Lucas, J. Catal., 110 (1988) 58.
E. G. Derouane, J. Mol. Cat. A:Chemical, 134 (1998) 29.
M. Spagnol, L. Gilbert, and D. Alby, Ind. Chem. Lib., 8 (1996) 29.
M. Spagnol, L. Gilbert, E. Benazzi, and C. Marcilly, PCT Int. Appl., WO 96 35,655 (1996).
M. Spagnol, L. Gilbert, E. Benazzi, and C. Marcilly, PCT Int. Appl., WO 96 35,656 (1996).
E. G. Derouane, C. J. Dillon, D. Bethell, and S. B. Abd Hamid, J. Catal., 187 (1999) 209.
E. G. Derouane, G. Crehan, C. J. Dillon, D. Bethell, H. He, and S. B. Abd Hamid, J. Catal., 194 (2000) 410.
C. J. Dillon, Ph.D. Thesis, University of Liverpool, December 2000.
M. Taramasso, G. Perego, and B. Notari, US Patent, 4,410,501 (1983).
G. Perego, G. Bellussi, C. Corno, M. Tara, F. Buonomo, and A. Esposito, in Proc. 7th Intern. Zeolite Conf., Y. Murakami, A. Ijiima, and J. Ward (eds.); Elsevier, Amsterdam, 1986, p. 129.
I. Ojima, Catalytic Asymmetric Synthesis, 2nd Ed., Wiley VCH, New York, 2000.
E. I. Klabunovski and R. A. Sheldon, CATTECH, 2 (1997) 153.
M. Ortega-Lorenzo, C. J. Baddeley, C. Muryn, and R. Raval, Nature, 404 (2000) 376.
E. G. Derouane, F. Lemos, A. Corma, and F. R. Ribeiro, Combinatorial Catalysis & High Throughput Catalyst Design & Testing, NATO ASI Science Series C, Vol. 560, Kluwer Academic/Plenum Publ., Dordrecht, The Netherlands, 2000.
A. Wood and A. Scott, Chemical Week, August 9, 2000.
Ultrafast GC columns are available from Stylacats Ltd., Robert Robinson Laboratories, Department of Chemistry, The University of Liverpool, P.O. Box 147, Liverpool L69 3BX, UK. Email to: “Mervyn Harding” <mervyn.harding@stylacats.com>.
E. G. Derouane, in Combinatorial Catalysis and High Throughput Catalyst Design and Testing, E. G. Derouane, F. Lemos, A. Corma, and F. R. Ribeiro (eds.), NATO ASI Science Series C, Vol. 560, Kluwer Academic/Plenum Publ., Dordrecht, The Netherlands, 2000, p. 475.
V. Smil, Enriching the Earth: F. Haber, C. Bosch, and the Transformation of World Food Production, MIT Press, Cambridge, Massachusetts, USA, 2001.
I.V. Kozhevnikov, Chem. Rev., 98 (1998) 171.
R. Raval, CATTECH, 5(1) (2001) 12.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Derouane, E.G. Catalysis in the 21st Century, Lessons from the Past, Challenges for the Future. CATTECH 5, 214–225 (2001). https://doi.org/10.1023/A:1014036813345
Issue Date:
DOI: https://doi.org/10.1023/A:1014036813345