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Intermolecular Interactions of 3,5-Di-tert-butyl-4-hydroxybenzyl Acetate in Crystal and in Solutions

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Abstract

The molecular and crystal structure of 3,5-di-tert-butyl-4-hydroxybenzyl acetate was studied by single-crystal X-ray diffraction. The molecules form infinite chains in the crystals via hydrogen bonds between the hydroxy and carbonyl groups. The interchain bonding is provided by CH-π interactions. In carbon tetrachloride, the molecules of the title compound form weak associates via hydrogen bonds between the hydroxy and carbonyl groups.

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Authors and Affiliations

  1. Kazan State Technological University, Kazan, Tatarstan, Russia

    S. V. Bukharov, S. N. Pod”yachev, V. V. Syakaev, I. A. Litvinov & A. T. Gubaidullin

  2. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, Kazan, Tatarstan, Russia

    S. V. Bukharov, S. N. Pod”yachev, V. V. Syakaev, I. A. Litvinov & A. T. Gubaidullin

Authors
  1. S. V. Bukharov
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  2. S. N. Pod”yachev
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  3. V. V. Syakaev
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  4. I. A. Litvinov
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  5. A. T. Gubaidullin
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Bukharov, S.V., Pod”yachev, S.N., Syakaev, V.V. et al. Intermolecular Interactions of 3,5-Di-tert-butyl-4-hydroxybenzyl Acetate in Crystal and in Solutions. Russian Journal of General Chemistry 71, 1570–1573 (2001). https://doi.org/10.1023/A:1013998819454

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  • DOI: https://doi.org/10.1023/A:1013998819454

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