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Synthesis of Boron-containing Complexes of 1-(2-hydroxyphenyl)-3-phenyl-2-propen-1-one

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Abstract

Condensation of o-hydroxyacetophenone with benzaldehyde in alcohol in the presence of a triple excess of a sodium hydroxide solution leads to 2'-hydroxychalcone sodium salt. The latter was heated with boron trifluoride etherate in toluene to a 2'-hydroxychalcone boron fluoride complex in which the boron atom is coordinated to the carbonyl oxygen atom. The same complex was obtained by boiling of the o-hydroxyacetophenone boron fluoride complex with benzaldehyde in acetic anhydride.

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  1. Mendeleev Russian University of Chemical Technology, Moscow, Russia

    A. V. Kukharenko & G. V. Avramenko

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  1. A. V. Kukharenko
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  2. G. V. Avramenko
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Kukharenko, A.V., Avramenko, G.V. Synthesis of Boron-containing Complexes of 1-(2-hydroxyphenyl)-3-phenyl-2-propen-1-one. Russian Journal of General Chemistry 71, 1562–1564 (2001). https://doi.org/10.1023/A:1013994718545

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