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Reaction of 3,4-Dichloro-5-methoxyfuran-2(5H)-one with 1,2-Organylbis(diphenylphosphines)

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Abstract

The reactions of 3,4-dichloro-5-methoxyfuran-2(5H)-one with 1,2-ethylenebis(diphenylphosphine) and 4,5-bis(diphenylphosphinyl)-2-phenylpyridazin-3(2H)-one involve substitution of both chlorine atoms with σ3-P atoms to form unstable diphosphonium bicyclic salts which in the course of the reaction undergo an unusual fragmentation to give finally mono- and tricyclic diphosphoniacyclohexane structures.

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Authors and Affiliations

  1. Kazan State University, Kazan, Tatarstan, Russia

    N. A. Polezhaeva, Yu. M. Volodina, A. V. Prosvirkin, V. G. Sakhibullina, V. I. Galkin & R. A. Cherkasov

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  1. N. A. Polezhaeva
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  2. Yu. M. Volodina
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  3. A. V. Prosvirkin
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  4. V. G. Sakhibullina
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  5. V. I. Galkin
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  6. R. A. Cherkasov
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Polezhaeva, N.A., Volodina, Y.M., Prosvirkin, A.V. et al. Reaction of 3,4-Dichloro-5-methoxyfuran-2(5H)-one with 1,2-Organylbis(diphenylphosphines). Russian Journal of General Chemistry 71, 1541–1544 (2001). https://doi.org/10.1023/A:1013982415819

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  • DOI: https://doi.org/10.1023/A:1013982415819

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