Abstract
Tribenzylphosphine oxide readily and stereoselectively reacts with aliphatic, aromatic, and heteroaromatic aldehydes in the presence of strong bases yielding exclusively (or predominantly) E-isomers of 1-organyl-2-phenylethenes and dibenzylphosphinic acid.
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Gusarova, N.K., Ivanova, N.I., Reutskaya, A.M. et al. Reaction of Tribenzylphosphine Oxide with Aldehydes. Russian Journal of Organic Chemistry 37, 1726–1730 (2001). https://doi.org/10.1023/A:1013974001957
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DOI: https://doi.org/10.1023/A:1013974001957