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Thermodynamic Properties of N-(Trimethylsily)ethyleneimine N-(Triethylsily)ethyleneimine and (Dimethylphenylsilyl)ethyleneimine Complexes with Zinc Chloride in the Range 0-340 K

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Abstract

Tmperature dependence of heat capacity of N-(trimethylsilyl)ethyleneimine, N-(triethylsilyl)-ethyleneimine, N-(dimethylphenylsilyl)ethyleneimine with zinc chloride was studied in the 5-340 K rangein an adiabatic vacuum calorimeter with ∼0.2% error. From the data obtained tge complexes thermodynamicfunctions C0 p(T), H 0(T)-H 0(0), S 0(T)-S 0(0) and G 0(T)-H 0(0) are obtained in the 0-340 K, as well as fractal dimensions D and characteristic temperatures Θmax for the functions of gractal heat capacity of solid substances.

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  1. Chemistry Research Institute, Lobachevskii Nizhegorodskii State University, Nizhny Novgorod, Russia

    T. G. Kulagina, B. V. Lebedev & A. M. Kochetkov

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  1. T. G. Kulagina
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  2. B. V. Lebedev
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  3. A. M. Kochetkov
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Kulagina, T.G., Lebedev, B.V. & Kochetkov, A.M. Thermodynamic Properties of N-(Trimethylsily)ethyleneimine N-(Triethylsily)ethyleneimine and (Dimethylphenylsilyl)ethyleneimine Complexes with Zinc Chloride in the Range 0-340 K. Russian Journal of General Chemistry 71, 1431–1437 (2001). https://doi.org/10.1023/A:1013962104664

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  • DOI: https://doi.org/10.1023/A:1013962104664

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