Abstract
Common and individual regularities in changes of volumes in reactions of aqueous solutions of phosphonic acids [methanephosphonic, 1-aminoethanephosphonic, carboxymethahephosphonic, 1-hydroxyethane-1,1-diphosphonic, and nitriletris(methanephosphonic)] with aqueous solutions of sodium, tetramethyl-, and tetraethylammonium hydroxides at 298 K were revealed. The proposed explanation allows for the ionization of acids, the neutralization and hydration of ions, the presence of betaine forms, and the formation of proton chelates.
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Myund, L.A., Latysheva, V.A., Arat-ool, S.M. et al. Chemical Reactions of Phosphonic Acids with Strong Bases in Aqueous Solutions. Volumetric Analusis. Russian Journal of General Chemistry 71, 1384–1392 (2001). https://doi.org/10.1023/A:1013953902847
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DOI: https://doi.org/10.1023/A:1013953902847