Abstract
The reaction of free methyl cation with (isobutylamino)trimethylsilane was studied by the radiochemical method. Like with organic amines and silazane, the reaction occurs by two channels: condensation and proton transfer. Proton transfer remains to be the major reaction channel, while its contribution is less that with amines and silazane. The radiochemical and quantum-chemical methods were used to show that the condensation and proton-transfer complexes decompose primarily via Si-N bond cleavage.
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REFERENCES
Bokii, G.V., Vvedenie v kristallokhimiyu (Introduction into Crystal Chemistry), Moscow: Mosk. Gos. Univ., 1954.
Ignat'ev, I.S., Kochina, T.A., Nefedov, V.D., Sinotova, E.N., and Kalinin, E.O., Zh. Obshch. Khim., 1995, vol. 65, no. 2, pp. 297-303.
Ignat'ev, I.S., Kochina, T.A., Nefedov, V.D., Sinotova, E.N., and Vrazhnov, D.V., Zh. Obshch. Khim., 1995, vol. 65, no. 2, pp. 304-307.
Vrazhnov, D.V., Ignat'ev, I.S., Kalinin, E.O., Kochina, T.A., Nefedov, V.D., and Sinotova, E.N., Zh. Obshch. Khim., 1997, vol. 67, no. 3, pp. 448-453.
Kochina, T.A., Ignat'ev, I.S., Sinotova, E.N., Nefedov, V.D., Vrazhnov, D.V., and Kalinin, E.O., Zh. Org. Khim., 1998, vol. 34, no. 11, pp. 1640-1643.
Ignat'ev, I.S., Kochina, T.A., Nefedov, V.D., Sinotova, E.N., Vrazhnov, D.V., and Ogurtsovskaya, I.S., Zh. Obshch. Khim., 1997, vol. 67, no. 6, pp. 962-966.
Hendewerk, M.L., Frey, R., and Dixon, D.A., J. Phys. Chem., 1983, vol. 87, no. 12, pp. 2026-2032.
Morton, T.H., Tetrahedron, 1982, vol. 38, no. 22, pp. 3195-3243.
Audier, H.E. and Morton, T.H., Org. Mass. Spectrom., 1993, vol. 28, no. 10, pp. 1218-1224.
Laguzzi, G., Osterheld, T.H., and Brauman, J.I., J. Phys. Chem., 1994, vol. 98, no. 23, pp. 5931-5934.
Frisch, M.J., Trucks, G.W., Schlegel, H.B., Gill, P.M.W., Johnson, B.G., Robb, M.A., Cheeseman, J.R., Keith, T., Petersson, G.A., Montgomery, J.A., Raghavachari, K., Al-Laham, M.A., Zakrzewski, V.G., Ortiz, J.V., Foresman, J.B., Cioslowski, J., Stefanov, B.B., Nanayakkara, A., Challacombe, M., Peng, C.Y., Ayala, P.Y., Chen, W., Wong, M.W., Andres, J.L., Replogle, E.S., Gomperts, R., Martin, R.L., Fox, D.J., Binkley, J.S., Defrees, D.J., Baker, J., Stewart, J.P., Head-Gordon, M., Gonzalez, C., and Pople, J.A., GAUSSIAN 94, Rev. D.3, Pittsburgh: Gaussian, 1995.
Dunning, T.H. and Hay, P.J., Methods of Electronic Structure Theory, Schaefer, H.F., III, Ed., New York: Plenum, 1977, vol. 3, ch. 1.
Klopman, G., J. Am. Chem. Soc., 1968, vol. 90, no. 1, pp. 223-232.
Nefedov, V.D., Sinotova, E.N., Akulov, G.P., and Syreishchikov, V.A., Radiokhimiya, 1968, vol. 10, no. 5, pp. 600-603.
Sinotova, E.N., Korsakov, M.V., and Shishkunov, V.A., Radiokhimiya, 1980, vol. 22, no. 3, pp. 466-468.
Andrianov, A.K., Metody elementoorganicheskoi khimii. Kremnii (Methods of Organoelement Chemistry. Silicon), Moscow: Nauka, 1968.
Nefedov, V.D., Sinotova, E.N., Kharitonov, N.P., and Kochina, T.A., Zh. Obshch. Khim., 1980, vol. 50, no. 11, pp. 2499-2504.
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Kochina, T.A., Vrazhnov, D.V., Sinotova, E.N. et al. Reaction of Free Methyl Cation with (Isobutylamino)trimethylsilane in the Gas Phase. A Radiochemical and Quantum-Chemical Study. Russian Journal of General Chemistry 71, 1557–1561 (2001). https://doi.org/10.1023/A:1013942701707
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DOI: https://doi.org/10.1023/A:1013942701707