Abstract
SCl-Substituted chromium(III), cobalt(III), and aluminum(III) acetylacetonates react with carbenes similarly to organylsulfenyl chlorides, with insertion of the carbenes into the S-Cl bond. Reaction with diazomethane gave chloromethylthio-substituted complexes whose structure was proved by IR, 1H NMR, and mass spectroscopy. The thermal oxidative degradation of the complexes was studied. Chlorination of SCH3-substituted acetylacetonates does not yield such complexes.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
REFERENCES
Shapkin, N.P., Svistunov, G.M., Reutov, V.A., and Glushchenko, V.Yu., Izv. Akad. Nauk SSSR, Ser. Khim., 1985, no. 11, pp. 2647–2648.
Svistunov, G.M., Reutov, V.A., and Shapkin, N.P., Zh. Obshch. Khim., 1988, vol. 58, no. 5, pp. 1178–1179.
Organic Chemistry of Sulfur, Oae, S., Ed., New York: Plenum, 1977.
Svistunov, G.M., Cand. Sci. (Chem.) Dissertation, Vladivostok, 1989.
Collman, J.P., Angew. Chem., 1965, vol. 77, no. 4, pp. 154–161.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Svistunova, I.V., Shapkin, N.P. & Svistunov, G.M. Chloromethylthio-Substituted Chromium(III), Cobalt(III), and Aluminum(III) Acetylacetonates. Russian Journal of General Chemistry 71, 1355–1357 (2001). https://doi.org/10.1023/A:1013941600121
Issue Date:
DOI: https://doi.org/10.1023/A:1013941600121