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Steric and Electronic Effects of Substituents on the Yield of 5,15-Substituted Octaalkylporphines

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Abstract

The electronic and steric effects of peripheral substituents on the yield of 5,15-diphenyloctaalkylporphines were studied. It was found that the electronic nature of substituents in the starting benzaldehydes exerts almost no yield effect. At the same time, there is some optimal size of substituents, which provides the highest possible yield of porphyrins.

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Authors and Affiliations

  1. Ivanovo State University of Chemical Engineering, Ivanovo, Russia

    S. A. Syrbu, T. V. Lyubimova & A. S. Semeikin

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  1. S. A. Syrbu
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  2. T. V. Lyubimova
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  3. A. S. Semeikin
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Syrbu, S.A., Lyubimova, T.V. & Semeikin, A.S. Steric and Electronic Effects of Substituents on the Yield of 5,15-Substituted Octaalkylporphines. Russian Journal of General Chemistry 71, 1656–1659 (2001). https://doi.org/10.1023/A:1013936027631

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  • DOI: https://doi.org/10.1023/A:1013936027631

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