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Reactions of Carbazoles with Hexacarbonyl Dicobalt Complexes of Propynol and 1,4-Butynediol

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Abstract

Metallopropargylation of a number of carbazoles was performed by dicobalt hexacarbonyl complexes with propargyl alcohol and 1,4-butynediol in the presence of boron trifluoride etherate. It was shown that depending on the substituents position in the carbazole ring occurred either N- of C-propargylation; with 1,4-butynediol formed also oligomeric products.

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REFERENCES

  1. Filimonov, V.D. and Sirotkina, E.E., Khimiya monomerov na osnove karbazola (Chemistry of Monomers on the Basis of Carbazole), Novosibirsk: Nauka, 1995.

    Google Scholar 

  2. Hubert, A.J. and Reimlinger, H., J. Chem. Soc. C, 1986, no. 5, pp. 606–608.

    Google Scholar 

  3. Lendel, V.G., Pak, B.I., Balog, I.M., Kiyak, M.V., and Migalina, Yu.V., Khim. Geterotsikl. Soed., 1990, no. 1, pp. 126–128.

    Google Scholar 

  4. Lockwood, R.F. and Nicolas, K.M., Tetrahedron Lett., 1977, no. 48, pp. 4163–4165.

    Google Scholar 

  5. Karpov, M.G., Zavgorodnii, V.S., Denisov, V.R., Ostrovskii, V.A. and Zubarev, V.Yu., Zh. Org. Khim., 2001, vol. 37, no. 8, pp. 1252–1253.

    Google Scholar 

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Authors and Affiliations

  1. St. Petersburg State Technological Institute, St. Petersburg, 198013, Russia

    M. G. Karpov, V. S. Zavgorodnii & V. R. Denisov

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  1. M. G. Karpov
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  2. V. S. Zavgorodnii
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  3. V. R. Denisov
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Karpov, M.G., Zavgorodnii, V.S. & Denisov, V.R. Reactions of Carbazoles with Hexacarbonyl Dicobalt Complexes of Propynol and 1,4-Butynediol. Russian Journal of Organic Chemistry 37, 1731–1735 (2001). https://doi.org/10.1023/A:1013926118795

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  • DOI: https://doi.org/10.1023/A:1013926118795

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