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The Hydrogenation of c-5 Alkynes over Palladium Catalysts

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Abstract

The hydrogenation of 1-pentyne and 2-pentyne was studied over palladium catalysts. The internal triple bond hydrogenated faster than the terminal and a particle size effect was observed on the rate of hydrogenation and isomerisation.

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Authors and Affiliations

  1. Synetix, P O Box 1, Belasis Ave., Billingham Cleveland, TS23 1LB, U.K

    S. David Jackson, Christine A. Hamilton, Gordon J. Kelly & David de Bruin

  2. Department of Chemistry, The University, Glasgow, G12 8QQ, Scotland

    S. David Jackson

Authors
  1. S. David Jackson
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  2. Christine A. Hamilton
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  3. Gordon J. Kelly
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  4. David de Bruin
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Jackson, S.D., Hamilton, C.A., Kelly, G.J. et al. The Hydrogenation of c-5 Alkynes over Palladium Catalysts. Reaction Kinetics and Catalysis Letters 73, 77–82 (2001). https://doi.org/10.1023/A:1013924921651

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  • DOI: https://doi.org/10.1023/A:1013924921651

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