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Mixed Anhydrides of Carboxylic and Trifluoroacetic Acids as Acylating Agents: I. Reactions of 3,5-Di-tert-butylbenzoyl Trifluoroacetate with tert-Butylphenols

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Abstract

The rate and pathway of reactions of 3,5-di-tert-butylbenzoyl trifluoroacetate with tert-butylphenols depend on the number and position of bulky substituents determining the extent of steric shielding of the phenolic hydroxyl.

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Authors and Affiliations

  1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhni Novgorod, Russia

    N. M. Khvoinova, D. V. Muslin & S. Ya. Khorshev

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  1. N. M. Khvoinova
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  2. D. V. Muslin
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  3. S. Ya. Khorshev
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Khvoinova, N.M., Muslin, D.V. & Khorshev, S.Y. Mixed Anhydrides of Carboxylic and Trifluoroacetic Acids as Acylating Agents: I. Reactions of 3,5-Di-tert-butylbenzoyl Trifluoroacetate with tert-Butylphenols. Russian Journal of General Chemistry 71, 1799–1801 (2001). https://doi.org/10.1023/A:1013915129700

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  • DOI: https://doi.org/10.1023/A:1013915129700

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