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Acceptor Properties of Trifluoroacetic Anhydride

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Abstract

Trifluoroacetic anhydride is a strong electron acceptor. Its enthalpies of mixing with various organic electron donors were determined, which are mostly controlled by acid-base interaction. A certain contribution into the enthalpies of mixing is also made by nonspecific solvation. This contribution can be accounted for by means of a three-parameter equation.

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Authors and Affiliations

  1. Altai Medical Institute, Barnaul, Russia

    I. A. Ivanov, R. G. Makitra, Ya. N. Pirig, V. G. Tsvetkov & V. A. Shmakov

  2. Department of Physical Chemistry and Technology of Fossil Fuels, Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Lviv, Ukraine

    I. A. Ivanov, R. G. Makitra, Ya. N. Pirig, V. G. Tsvetkov & V. A. Shmakov

  3. L'vovskaya politekhnika State University, Lviv, Ukraine

    I. A. Ivanov, R. G. Makitra, Ya. N. Pirig, V. G. Tsvetkov & V. A. Shmakov

  4. Research Institute of Chemistry, Lobachevskii Nizhny Novgorod State University, Nizhny Novgorod, Russia

    I. A. Ivanov, R. G. Makitra, Ya. N. Pirig, V. G. Tsvetkov & V. A. Shmakov

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  1. I. A. Ivanov
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  2. R. G. Makitra
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  3. Ya. N. Pirig
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  4. V. G. Tsvetkov
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  5. V. A. Shmakov
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Ivanov, I.A., Makitra, R.G., Pirig, Y.N. et al. Acceptor Properties of Trifluoroacetic Anhydride. Russian Journal of General Chemistry 71, 1578–1580 (2001). https://doi.org/10.1023/A:1013903120362

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  • DOI: https://doi.org/10.1023/A:1013903120362

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