Abstract
Pt nanowires are prepared in mesoporous FSM-16 by photoreduction of H2PtCl6, while H2-reduction of H2PtCl6/FSM-16 at 673 K gives Pt nanoparticles in FSM-16. The Pt nanowires and nanoparticles are characterized by physicochemical methods such as XAFS, TEM, XRD, and XPS. The formation mechanism of the Pt nanowires and the catalytic performance in the water–gas-shift reaction are also investigated.
Similar content being viewed by others
References
J.M. Thomas and W.J. Thomas, Principles and Practice of Heterogeneous Catalysis (VCH, Weinheim, 1997).
M. Ichikawa, in: Metal Clusters in Chemistry, Vol. 3, eds. P. Braunstein, L.A. Oro and P.R. Raithby (Wiley/VCH, New York/Weinheim, 1999) p. 1273.
G. Shulz-Ekloff and S. Ernst, in: Handbook of Heterogeneous Catalysis, eds. G. Ertl, H. Knözinger and J. Weitkamp (Wiley/VCH, New York/Weinheim, 1997) p. 153.
S. Kawi and B.C. Gates, in: Clusters and Colloids, ed. G. Schmid (VCH, Weinheim, 1994) p. 299.
C.T. Kresge, M.E. Leonowicz, W.J. Roth, J.C. Vartuli and J.S. Beck, Nature 359 (1992) 710.
J.S. Beck, J.C. Vartuli, W.J. Roth, M.E. Leonowicz, C.T. Kresge, K.D. Schmitt, C.T.-W. Chu, D.H. Olson, E.W. Sheppard, S.B. McCullen, J.B. Higgins and J.L. Schlenker, J. Am. Chem. Soc. 114 (1992) 10834.
S. Inagaki, Y. Fukushima and K. Kuroda, J. Chem. Soc. Chem. Commun. (1993) 680.
S. Inagaki, A. Koiwai, N. Suzuki, Y. Fukushima and K. Kuroda, Bull. Chem. Soc. Jpn. 69 (1996) 1449.
A. Corma, Chem. Rev. 97 (1997) 2373.
S. Biz and M.L. Occelli, Catal. Rev. Sci. Eng. 40 (1998) 329.
T. Yamamoto, T. Shido, S. Inagaki, Y. Fukushima and M. Ichikawa, J. Am. Chem. Soc. 118 (1996) 5810.
T. Yamamoto, T. Shido, S. Inagaki, Y. Fukushima and M. Ichikawa, J. Phys. Chem. B 102 (1998) 3866.
A. Fukuoka, M. Osada, T. Shido, S. Inagaki, Y. Fukushima and M. Ichikawa, Inorg. Chim. Acta 294 (1999) 281.
M. Sasaki, M. Osada, N. Higashimoto, S. Inagaki, Y. Fukushima, A. Fukuoka and M. Ichikawa, Micropor. Mesopor. Mater. 21 (1998) 597.
M. Sasaki, M. Osada, N. Higashimoto, T. Yamamoto, A. Fukuoka and M. Ichikawa, J. Mol. Catal. A 141 (1999) 223.
C.H. Ko and R. Ryoo, J. Chem. Soc. Chem. Commun. (1996) 2467.
T. Kyotani, L. Tsai and A. Tomita, J. Chem. Soc. Chem. Commun. (1997) 701.
Y. Plyuto, J.-M. Berquier, C. Jacquiod and C. Ricolleau, J. Chem. Soc. Chem. Commun. (1999) 1652.
M.H. Huang, A. Choudrey and P. Yang, J. Chem. Soc. Chem. Commun. (2000) 1063.
Y.-J. Han, J.M. Kim and G.D. Stucky, Chem. Mater. 12 (2000) 2068.
Z. Liu, Y. Sakamoto, T. Ohsuna, K. Hiraga, O. Terasaki, C.H. Ko, H.J. Shin and R. Ryoo, Angew. Chem. Int. Ed. Engl. 39 (2000) 3107.
A.S. Fung, M.J. Kelley, D.C. Koningsberger and B.C. Gates, J. Am. Chem. Soc. 119 (1997) 5877.
A.N. Mansour, J.W. Cook, Jr., D.E. Sayers, R.J. Emrich and J.R. Katzer, J. Catal. 89 (2000) 462.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Fukuoka, A., Higashimoto, N., Sakamoto, Y. et al. Preparation, XAFS Characterization, and Catalysis of Platinum Nanowires and Nanoparticles in Mesoporous Silica FSM-16. Topics in Catalysis 18, 73–78 (2002). https://doi.org/10.1023/A:1013886301858
Issue Date:
DOI: https://doi.org/10.1023/A:1013886301858