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Towards Heterogeneous and Green Versions of Os Dihydroxylation Catalysis

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Abstract

Os-catalyzed dihydroxylation will find more widespread application if truly heterogeneous catalysts are available which use O2 or H2O2 as terminal oxidants. This paper discusses and critically evaluates the concepts by which Os can be anchored on solid supports. New methods are also available for reoxidation of hexavalent to octavalent Os.

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Authors and Affiliations

  1. Centre for Surface Chemistry and Catalysis, K.U. Leuven, Kasteelpark Arenberg 23, 3001, Leuven, Belgium

    An Severeyns, Dirk E. De Vos & Pierre A. Jacobs

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  1. An Severeyns
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  2. Dirk E. De Vos
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  3. Pierre A. Jacobs
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Severeyns, A., De Vos, D.E. & Jacobs, P.A. Towards Heterogeneous and Green Versions of Os Dihydroxylation Catalysis. Topics in Catalysis 19, 125–131 (2002). https://doi.org/10.1023/A:1013845619179

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