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Effects of Surface Relaxation on Enantiospecific Adsorption on Naturally Chiral Pt Surfaces

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Abstract

Many high Miller index metals surfaces are naturally chiral, offering opportunities for performing enantiospecific chemistry. Previous theoretical treatments of adsorption on these surfaces have used surfaces truncated from bulk crystals. This paper examines the effect of surface relaxation on enantiospecific adsorption on chiral Pt surfaces by using relaxed surface structures determined using density functional theory.

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Authors and Affiliations

  1. Department of Chemical Engineering, Carnegie Mellon University, Pittsburgh, PA, 15213, USA

    Timothy D. Power & David S. Sholl

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  1. Timothy D. Power
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  2. David S. Sholl
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Power, T.D., Sholl, D.S. Effects of Surface Relaxation on Enantiospecific Adsorption on Naturally Chiral Pt Surfaces. Topics in Catalysis 18, 201–208 (2002). https://doi.org/10.1023/A:1013834521060

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