Abstract
The kinetics of molecular oxygen electroreduction were studied on platinum surfaces modified by tin underpotential deposition. The surface process was analysed by cyclic voltammetry in aqueous 10−4 M tin(II)/1 M sulfuric acid in the 0.05 to 0.70 V vs RHE range. Platinum sites involving (1 1 0) planes are mainly related to tin underpotential deposition as observed in the hydrogen sorption region. Kinetic runs for oxygen reduction were performed with the rotating ring-disc electrode technique on tin-modified platinum surfaces. It was concluded that molecular oxygen reduction on tin-modified platinum takes place through bulk hydrogen peroxide and water formation. This interpretation was confirmed by calculating the reaction order with respect to oxygen. Electrochemical rate constants for oxygen reduction pathways were calculated as a function of deposition potential based on Damjanović's reaction scheme.
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References
E. Yeager, Electrochim. Acta 29 (1984) 1527.
K.L. Hsueh, E.R. González and S. Srinivasan, Electrochim. Acta 28 (1983) 691.
A.J. Appleby and S. Baker, J. Electrochem. Soc. 125 (1978) 404.
P.N. Ross and P.C. Andriacos, J. Electroanal. Chem. 154 (1983) 205.
R.R. Adzic, in R.E. White, J.O'M. Bockris and B.E. Conway (Eds), ‘Modern Aspects of Electrochemistry’, Vol. 21 (Plenum Press, New York, 1990), chap. 5 pp. 163-235.
D.M. Kolb, in H. Gerisher and C.W. Tobias (Eds), ‘Advances in Electrochemistry and Electrochemical Engineering’, Vol. 11 (Interscience, New York, 1978) p. 125.
M.W. Breiter, J. Electrochem. Soc. 114 (1967) 1125.
D. Margheritis, R.C. Salvarezza, M.C. Giordano and A.J. Arvia, J. Electroanal. Chem. 229 (1987) 327.
S.A.S. Machado, A.A. Tanaka and E.R. González, Electrochim. Acta 36 (1991) 1325.
C.F. Zinola, A.M. Castro Luna, W.E. Triaca and A.J. Arvia, Electrochim. Acta, special issue dedicated to ‘Progress in Electrocatalysis: Theory and Practice’, 39 (1994) 1627.
C.F. Zinola, W.E. Triaca and A.J. Arvia, J. Appl. Electrochem. 25 (1995) 740.
A Damjanovic and V. Brusic, Electrochim. Acta 12 (1967) 615.
H. Wroblowa, M.L.B. Rao, A. Damjanovic and J.O'M. Bockris, J. Electroanal. Chem. 15 (1967) 139.
H. Kita, H. Lei and Y. Gao, J. Electroanal. Chem. 379 (1994) 407.
M. Drogowska, H. Menard and L. Brossard, J. Appl. Electrochem. 21 (1991) 84.
X.H. Xia, Electrochim. Acta 45 (1999) 1057.
A.S. Lapa, Deposited Doc. (1981) 575-582.
M.O. Argüeso Mengod, Doctoral thesis ‘Electrodo de Platino Modi.cado por Adatomos de Estaño, Cobre y Plomo. Influencia de la Electrooxidación de n-propanol en ácido sulfúrico’ (Universidad de São Paulo, 1993).
P. Berenz, S. Tillmann, H. Massong and H. Baltruschat, Electrochim. Acta 43 (1998) 3035.
H. Massong, S. Tillmann, T. Langkau, E.A. Abd El Meguid and H. Baltruschat, Electrochim. Acta 44 (1998) 1379.
B.J. Bowles, Nature 212 (1996) 1456.
B.J. Bowles and T.E. Cranshaw, Phys. Lett. 17 (1965) 258.
S.H. Cadle and S. Brückenstein, Anal. Chem. 43 (1971) 932.
N. Furuya and S. Motto, J. Electroanal. Chem. 72 (1976) 165.
H. Angerstein-Kozlowska, in E.B. Yeager, J.O'M. Bocris, B.E. Conway and S. Sarangapani (Eds) 'A Comprehensive Treatise of Electrochemistry’, Vol. 9 (Plenum Press, New York, 1984), chap. 2, p. 15.
C.F. Zinola, J. Tróccoli and J. Rodríguez, in preparation.
A. Damjanovic, M.A. Genshaw and J.O'M. Bockris, J. Chem. Phys. 45 (1964) 4057.
Su-Moon Park, S. Ho, S. Aruliah, M. Weber, C. Ward, R. Venter and S. Srinivasan, J. Electrochem. Soc. 113 (1986) 1641.
J.D.E. Mc. Intyre and W.F. Peck Jr., ‘Chemistry and Physics of Electrocatalysis,’ Vol. 84-12, (1984), pp. 102-130.
C.F. Zinola, A.M. Castro Luna, W.E. Triaca and A.J. Arvia, J. Appl. Electrochem. 24 (1994) 531.
A.J. Appleby, J. Electroanal. Chem. 357 (1993) 117.
F. El Kadiri, R. Faure and R. Durand, J. Electroanal. Chem. 301 (1991) 177.
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Zinola, C., Rodríguez, J. & Obal, G. Kinetics of molecular oxygen electroreduction on platinum modified by tin underpotential deposition. Journal of Applied Electrochemistry 31, 1293–1300 (2001). https://doi.org/10.1023/A:1013821319096
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DOI: https://doi.org/10.1023/A:1013821319096