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Donor–Acceptor Mechanism of Complex Formation

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Abstract

The gas-phase van der Waals complexes formed in the course of donor–acceptor interaction are shown to become coordination compounds only in the crystalline state. With close lengths of the covalent-ionic and coordination bonds, their energies differ by ∼100 kJ. This energy difference is due to the work spent to overcome van der Waals forces during the formation of complex ions from interacting molecules.

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  1. Center for High Dynamic Pressures, Mendeleevo, Moscow oblast, Russia

    S. S. Batsanov

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Batsanov, S.S. Donor–Acceptor Mechanism of Complex Formation. Russian Journal of Coordination Chemistry 28, 1–5 (2002). https://doi.org/10.1023/A:1013769217577

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