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Thermal Properties of N-ethyl-N-phenyl-Dithiocarbamates and Their Influence on the Kinetics of Cure

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Abstract

The thermal properties (in the temperature range of 100–250°C) of N-ethyl-N-phenyldithiocarbamatecomplexes of Zn(II), Co(III), Ni(II), Cu(II) and Pb(II) and their influence on the kinetics of cure have been studied by differential scanning calorimetry (in nitrogen). It was found that Zn(II), Co(III) and Pb(II) dithiocarbamates melted without further effects, while the melting of Ni(II) and Cu(II) dithiocarbamates is accompanied with decomposition. From the kinetic point of view, the dithiocarbamates decrease the values of the reaction order and the values of rate constants follow this order (with respect to the metal ion): Zn(II)<Cu(II)<Pb(II)<Ni(II)<Co(III).

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Authors and Affiliations

  1. Department of Chemistry and Technology of Inorganic Materials, Faculty of Industrial Technologies, University of Trenčín, 020 32, Púchov, Slovak Republic

    D. Ondrušová & E. Jóna

  2. Department of Physical Chemistry, Slovak Technical University, 812 37, Bratislava, Slovak Republic

    P. Šimon

Authors
  1. D. Ondrušová
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  2. E. Jóna
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  3. P. Šimon
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Ondrušová, D., Jóna, E. & Šimon, P. Thermal Properties of N-ethyl-N-phenyl-Dithiocarbamates and Their Influence on the Kinetics of Cure. Journal of Thermal Analysis and Calorimetry 67, 147–152 (2002). https://doi.org/10.1023/A:1013750316903

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