Abstract
The structure of [H2B(3,5-Me2pz)2]2Cd shows the four nitrogen donor atoms form a pseudotetrahedral arrangement about the cadmium(II). The intraligand N—Cd—N angles are restricted to an average of 91.4° by the chelate rings forcing the interligand N—Cd—N bond angles to average 119.4°. The Cd—N bond distances average 2.21 Å with a range of 0.04 Å. The crystal is in the triclinic space group, P \(\overline 1\) with a = 7.6793(2) Å, b = 8.5992(2) Å, c = 25.0874(4) Å, α = 91.0791(2)°, β = 97.9769(4)°, γ = 110.2344(6)°, and Z = 2.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
(a) Reger, D.L.; Mason, S.S.; Rheingold, A.L.; Ostrander, R L. Inorg. Chem. 1993, 32, 5216; (b) Lipton, A.S.; Mason, S.S.; Reger, D.L.; Ellis, P.D. J. Am. Chem. Soc. 1994, 116 10182; (c) Reger, D.L.; Mason, S.S. Polyhedron 1994, 13 3059; (d) Reger, D.L.; Myers, S.M.; Mason, S.S.; Rheingold, A.L.; Haggerty, B.S.; Ellis, P.D. Inorg. Chem. 1995, 34 4996; (e) Reger, D.L.; Mason, S.S.; Rheingold, A.L. Inorg. Chem. Acta 1996, 240 669; (f) Reger, D.L.; Myers, S.M.; Mason, S.S.; Darensbourg, D.J.; Holtcamp, M.W.; Reibenspies, J.H.; Lipton, A.S.; Ellis, P.D. J. Am. Chem. Soc. 1995, 117 10998; (g) Lipton, A.S.; Mason, S.S.; Myers, S.M.; Reger, D.L.; Ellis, P.D. Inorg. Chem. 1996, 35 7111; (h) Reger, D.L.; Collins, J.E.; Myers, S.M.; Rheingold, A.L.; Liable-Sands. L.M. Inorg. Chem. 1996, 35 4904.
(a) Looney, A.; Saleh, A.; Zhang, Y.; Parkin, G. Inorg. Chem. 1994, 33, 1158; (b) Lobbia, G.G.; Leonesi, D.; Cingolani, A.; Lorenzotti, A.; Bonati, F. Synth. React. Inorg. Met.-Org. Chem. 1987, 17 909; (c) Lobbia, G.G.; Bonati, F.; Cingolani, A.; Leonesi, D. Synth. React. Inorg. Met.-Org. Chem. 1989, 19 827; (d) Pettinari, C.; Santini, C.; Leonesi, D. Polyhedron 1994, 13 1553; (e) Lobbia, G.G.; Bovio, B.; Santini, C.; Cecchi, P.; Pettinari, C.; Marchetti, F. Polyhedron 1998, 17 17.
(a) Coleman, J.E. In Metallobiochemistry, Part D; Riordan, J.F.; Vallee, B.L., Ed.; Academic Press: San Diego, CA, 1993; Meth. Enzymol. 227, pp. 16-43; (b) Rivera, E.; Kennedy, M.A.; Ellis, P.D. Adv.Magn. Reson. 1989, 13 257; (c) Summers, M.F. Coord. Chem. Rev. 1988, 86 43; (d) Ellis, P.D. J. Biol. Chem. 1989, 264 3108; (e) Kennedy, M.A.; Ellis, P.D. J. Am. Chem. Soc. 1989, 111 3159.
Lipton, A.S.; Wright, T.A.; Bowman, M.K.; Reger, D.L.; Ellis, P.D. J. Am. Chem. Soc., submitted.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Reger, D.L., Wright, T.D., Rheingold, A.L. et al. Crystal structure of bis[dihydrobis(3,5-dimethy-1-pyrazolyl)borato]cadmium(II). Journal of Chemical Crystallography 31, 93–95 (2001). https://doi.org/10.1023/A:1013747123528
Issue Date:
DOI: https://doi.org/10.1023/A:1013747123528