Skip to main content
SpringerLink
Log in

Thermal, Spectral and Antimicrobial Properties of New Zinc(II) Isobutyrate Compounds: Part I. Papaverine, Phenazone

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

Zinc carboxylate complexes with N-donor ligands exhibit antimicrobial and antifungal effects. The preparation and thermal properties of complex compounds Zn(isobut)2 and Zn(isobut)2L(isobut=(CH3)2CHCOO−, L=papaverine — pap, phenazone — phen) are described in this paper. The newly synthesized compounds were characterized by elemental analysis, IR spectroscopy and TG/DTG, DTA methods.

During the thermal treatment it was found that the release of organicligands (pap, phen) was followed by pyrolysis of zinc(II) isobutyrate. (C3H7)2CO and CO2 were found as gaseous products and zinc oxide as the final product of thermal decomposition. Gaseous and solid products of thermal decomposition were confirmed by chemical analysis, IR spectra and X-ray powder diffraction.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J. Maureen, T. M. Michal, J. P. Martin and D. R. Kerry, Metals in Biological Systems, Ellis Horwood, London 1992.

    Google Scholar 

  2. E. Körös, Bioinorganic Chemistry, Gondolat, Budapest 1992.

    Google Scholar 

  3. J. G. Brewer, Met. Ions Biol. Syst., 14 (1982) 57.

    Google Scholar 

  4. E. G. Dechyukina, T. L. Christyakova, V. I. Kruzova and V. K. Eroshin, Mikrobiologiya, 57 (1988) 757.

    Google Scholar 

  5. K. Györyová, V. Balek and V. Zeleňák, Thermochim. Acta, 234 (1994) 221.

    Google Scholar 

  6. K. Györyová and V. Balek, J. Thermal Anal., 45 (1993) 19.

    Google Scholar 

  7. K. Györyová, V. Balek and J. Kovařová, Thermochim. Acta, 269/270 (1995) 425.

    Google Scholar 

  8. K. Györyová, J. Kovařová, V. Zeleňák, E. Andogová and M. Melnik, Book of Abstracts, ESTAC 7, Balatonfüred 1998, p. 79.

  9. K. Györyová, J. Kovařová, M. Melnik and E. Andogová, J. Therm. Anal. Cal., 55 (1999) 503.

    Google Scholar 

  10. IRSCOT, Infrared Structural Correlation Tables of Data Cards, VWH, London 1969.

    Google Scholar 

  11. J. P. Grasselli and W. M. Ritchey, Atlas of Spectral Data and Physical Constants for Organic Compounds, CRC Press, Cleveland 1975.

    Google Scholar 

  12. K. Györyová, V. Balek, B. H. Behrens, A. Matuschek and A. Kettrup, J. Thermal Anal., 48 (1997) 1263.

    Google Scholar 

  13. V. Zeleňák, K. Györyová and D. Mlynarčik, Metal Based Drugs, in press.

Download references

Author information

Authors and Affiliations

  1. Department of Inorganic Chemistry, P. J. Šafarik University, Moyzesova 11, 041 54, Košice, Slovak Republic

    K. Györyová, E. Andogová & V. Zeleňák

  2. Institute of Macromolecular Chemistry AV ČR, Heyrovského nám. 2, 162 06, Praha 6, Czech Republic

    J. Kovářová

  3. Chemistry Department, Faculty of Science, Cairo University, Giza, Egypt

    F. A. Nour El-Dien

Authors
  1. K. Györyová
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. J. Kovářová
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. Andogová
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. Zeleňák
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. F. A. Nour El-Dien
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Györyová, K., Kovářová, J., Andogová, E. et al. Thermal, Spectral and Antimicrobial Properties of New Zinc(II) Isobutyrate Compounds: Part I. Papaverine, Phenazone. Journal of Thermal Analysis and Calorimetry 67, 119–128 (2002). https://doi.org/10.1023/A:1013742015086

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1013742015086

Search

Navigation