Abstract
Rearrangements of neoclovene epoxides in the presence of a solid superacid ZrO2/SO4 2 - and in formic acid were investigated. In the latter case a ketone was obtained with a previously unknown carbon skeleton. The most probable pathway of its formation was derived from calculations by molecular mechanics and quantum-chemical methods.
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Khomenko, T.M., Korchagina, D.V., Gatilov, Y.V. et al. Rearrangements of Neoclovene Epoxides in Acidic Media. Russian Journal of Organic Chemistry 37, 1430–1434 (2001). https://doi.org/10.1023/A:1013452011816
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DOI: https://doi.org/10.1023/A:1013452011816