Abstract
The crystal structure of trans-bis(monoethanolamine)bis(saccharinato)nickel(II), [Ni(C7H4NO3S)2(C2H7NO)2], has been determined from X-ray diffraction data. The metal complex is monoclinic, with a = 11.0555(5), b = 8.9103(4), c = 11.3890(5) Å, β = 105.0230(10)°, Z = 2, and space group P21/c . The structure consists of individual molecules. Two monoethanolamine molecules and two saccharinate anions coordinate the nickel atom forming a distorted octahedron. The monoethanolamine molecules act as a bidentate ligand and form five-membered trans chelate rings, which constitute the plane of the coordination octahedron, while two saccharinate ions behave as a monodentate ligand occupying the axial positions. Intermolecular hydrogen bonds link the molecules to form a three-dimensional infinite structure.
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Andac, O., Topcu, Y., Yilmaz, V.T. et al. X-ray crystal structure of trans-bis(monoethanolamine) bis(saccharinato)nickel(II). Journal of Chemical Crystallography 30, 767–771 (2000). https://doi.org/10.1023/A:1013292406687
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DOI: https://doi.org/10.1023/A:1013292406687