Skip to main content
SpringerLink
Log in

X-ray structure of [(μ-H)Os3(CO)10(μ-1,8-η2-C9H6N)]

  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

Decacarbonyl-μ-hydrido-μ-1,8-η2-quinoline-triosmium crystallizes in the triclinic space group P \(\bar 1\) with a = 7.8551(6), b = 9.1283(8), c = 16.7915(8) Å, α = 74.788(2), β = 88.086(2), γ = 66.392(3)°, V = 1062.22(13)° Å3, T = 150 K, and Z = 2. The molecule consists of an Os3 triangle with the hydride and the heterocyclic ligand bridging the same Os—Os edge. The heterocyclic ligand is coordinated through the C(8) carbon and nitrogen atoms in a new μ-1,8-η2-bonding mode. The Os—Os distances lie in the close range 2.8837(4)–2.9034(4) Å with an average value of 2.892(7) Å.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Eisenstadt, A.; Giandomenico, C.M.; Frederick, M.F.; Laine, R.M. Organometallics 1985, 4, 2033.

    Google Scholar 

  2. Fish, H.F.; Kim, T.-J.; Stewart, J.L.; Bushweller, J.H.; Rosen, R.K.; Dupon, J.W. Organometallics 1986, 5, 2193.

    Google Scholar 

  3. Kabir, S.E.; Siddiquee, T.A.; Rosenberg, E.; Smith, R.; Hursthouse, M.B.; Malik, K.M.A.; Hardkastle, K.I.; Visi, M. J. Cluster Sci. 1998, 9, 185.

    Google Scholar 

  4. Kabir, S.E.; Kolwaite, D.S.; Rosenberg, E.; Hardcastle K.I.; Cresswell, W.; Grindstaff, J. Organometallics 1995, 14, 3611.

    Google Scholar 

  5. Arcia, E.; Kolwaite, D.S.; Rosenberg, E.; Hardcastle, K.I.; Ciurash, J.; Duque, R.; Gobetto, R.; Milone, L.; Osella, D.; Botta, M.; Dastru, W.; Viale, A.; Fiedler, I. Organometallics 1998, 17, 415, and references therein.

    Google Scholar 

  6. Kabir, S.E.; Vahrenkamp, H.; Hursthouse, M.B.; Malik, K.M.A. J. Organomet. Chem. 1997, 536-537, 509.

  7. Kabir, S.E.; Malik, K.M.A. unpublished data.

  8. Hooft, R. COLLECT data collection software; Nonius B.V., Delft: The Netherlands, 1998.

    Google Scholar 

  9. Otwinowski, Z.; Minor, W. In Macromolecular Crystallography; Carter Jr., C.W.; Sweet, R.M., Eds.; Academic Press: New York, 1997; pp. 307-326.

    Google Scholar 

  10. Blessing, R.H. Acta Crystallgr. 1995, A51, 33.

    Google Scholar 

  11. Blessing, R.H. J. Appl. Crystallgr. 1997, 30, 421.

    Google Scholar 

  12. Sheldrick, G.M.; Acta Crystallogr. Sect. A 1990, 46, 467.

    Google Scholar 

  13. Sheldrick, G.M. SHELXL-96, Program for Crystal Structure Refinement; University of Göttingen: Germany, 1996.

    Google Scholar 

  14. Azam, K.A.; Dilshad, R.; Kabir, S.E.; Khatoon, K.; Nessa, L.; Rahman, M.M.; Rosenberg, E.; Hursthouse, M.B.; Malik, K.M.A.; Deeming, A.J. J. Chem. Soc., Dalton Trans. 1996, 1731.

  15. Azam, K.A.; Hursthouse, M.B.; Hussain, S.A.; Kabir, S.E.; Malik, K.M.A.; Rahman, M.M.; Rosenberg, E. J. Organomet. Chem. 1998, 559, 81.

    Google Scholar 

  16. Kabir, S.E.; Tesmer, M.; Vahrenkamp, H.; Hursthouse, M.B.; Malik, K.M.A. J. Organomet. Chem. 1998, 568, 133.

    Google Scholar 

Download references

Authors
  1. Jakia Akter
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. G.M. Golzar Hossain
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Shariff E. Kabir
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. K.M. Abdul Malik
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Akter, J., Hossain, G.G., Kabir, S.E. et al. X-ray structure of [(μ-H)Os3(CO)10(μ-1,8-η2-C9H6N)]. Journal of Chemical Crystallography 30, 773–776 (2000). https://doi.org/10.1023/A:1013268023526

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1013268023526

Search

Navigation