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Crystal structure, thermal analysis, and IR spectrometric investigation of bis(tert-butylammonium) sulfate

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Abstract

Chemical preparation, X-ray single crystal, thermal analysis, and IR spectrometric investigation of (C4H12N)2SO4, denoted tBAS, are described. The compound crystallizes in the monoclinic system with C2/c space group. Its unit cell dimensions are a = 11.1585(5) Å, b = 6.2148(4) Å, c = 20.070(1) Å, β = 102.004(4)°, V = 1361.4(1) Å3, and Z = 4. The crystal structure of tBAS can be described as a typical thick layered organization built by all the components of the structure and centered by planes z = 1/4 and 3/4. Connection in these layers are established by N—H···O hydrogen bonds. Thermal analysis shows a reversible weak phase transition.

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Authors and Affiliations

  1. Laboratoire de Chimie du Solide, Département de Chimie, Faculté des Sciences de Monastir, Université du centre, 5019, Monastir, Tunisia, North Africa

    Taha Guerfel & Mohamed Bdiri

  2. Laboratoire de Chimie du Solide, Département de Chimie, Faculté des Sciences de Monastir, Université du centre, 5019, Monastir, Tunisia, North Africa

    Amor Jouini

Authors
  1. Taha Guerfel
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  2. Mohamed Bdiri
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  3. Amor Jouini
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Guerfel, T., Bdiri, M. & Jouini, A. Crystal structure, thermal analysis, and IR spectrometric investigation of bis(tert-butylammonium) sulfate. Journal of Chemical Crystallography 30, 799–804 (2000). https://doi.org/10.1023/A:1013228409413

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  • DOI: https://doi.org/10.1023/A:1013228409413

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