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Synthesis and Structure of Tetra- and Triarylantimony Oximates

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Abstract

Pentaphenyl- and penta-p-tolylantimony were reacted with benzophenone oxime or triarylantimony bis(benzophenonoximate) in toluene to obtain tetraarylantimony benzophenonoximate. Triarylantimony bis(benzophenonoximates) were prepared by oxidative addition from tryarylstibine and oxime in ether in the presence of hydrogen peroxide. X-ray diffraction analysis of tetraphenylantimony benzophenonoximate was performed to show that coordination of the antimony atom is trigonal-bipyramidal and the oxime oxygen atom is axial.

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Authors and Affiliations

  1. Blagoveshchensk State Pedagogical University, Blagoveshchensk, Russia

    V. V. Sharutin, O. K. Sharutina, O. V. Molokova, E. N. Ettenko, D. B. Krivolapov, A. T. Gubaidullin & I. A. Litvinov

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  1. V. V. Sharutin
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  2. O. K. Sharutina
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  3. O. V. Molokova
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  4. E. N. Ettenko
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  5. D. B. Krivolapov
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  6. A. T. Gubaidullin
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  7. I. A. Litvinov
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Sharutin, V.V., Sharutina, O.K., Molokova, O.V. et al. Synthesis and Structure of Tetra- and Triarylantimony Oximates. Russian Journal of General Chemistry 71, 1243–1247 (2001). https://doi.org/10.1023/A:1013220911661

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  • DOI: https://doi.org/10.1023/A:1013220911661

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