Skip to main content
Log in

Characterization of a few Mexican clays

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

The characterization of a few Mexican clays with chemical treatmentfor possible application as catalysers is shown. The natural clays are treatedwith H2 SO4 , HF, F3 CSO3 H, ClSO3 H, HClO4 and their behavior in reactions with some alcoholswas recorded. The analysis were made before and after using the clays as catalysers.The clays were characterized by Mössbauer spectroscopy, X-ray diffraction,X-ray fluorescence analysis, and differential thermo analysis. The predominantmineral species are: montmorillonite, christobalite and quartz. The main elementsare: Si, Al, Fe, Ca, K, etc. The Mössbauer results show mainly a paramagneticdoublet of Fe3+ . The clays behave similarly as described in theliterature.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. K. Smith, Solid Support and Catalysis in Organic Synthesis, Ellis Horwood and Prentice Hall, San Francisco, 1992.

    Google Scholar 

  2. Tonsil Mexicana, S.A. de C.V., Tierras Decolorantes y Superactivos, Apartado Postal 19–201. México, D.F., México. Telex 0 1771 02.

  3. P. Laszlo, Acc. Chem. Res., 19 (1986) 121.

    Google Scholar 

  4. P. Laszlo,Moison, Chem. Lett., (1989) 1031.

  5. P. Laszlo,Luchetti, Tetrahedron Lett., 25 (1984) 1567.

    Google Scholar 

  6. C. N. Rhodes,D. R. Brown, Catal. Lett., 24 (1994) 285.

    Google Scholar 

  7. A. Ballantine, J. H. purnell, J. M. Thomas, European Patent, 80304620.0 (01/07/81).

  8. J. A. Ballantine,J. H. Purnell,J. M. Thomas, Clay Miner., 18 (1983) 347.

    Google Scholar 

  9. J. A. Ballantine,M. Davies,I. Patel,J. H. Purnell,M. Rayanacom,K. J. Williams,J. M. Thomas, J. Mol. Catal., 26 (1984) 37.

    Google Scholar 

  10. J. R. Sohon,M. Y. Park, Appl. Catal., A101 (1993) 129.

    Google Scholar 

  11. A. Cabrera,N. Rosas,C. MÁrquez,M. SalmÓn,E. Angeles, Gazz. Chim. Ital., 121 (1991) 127.

    Google Scholar 

  12. A. Cabrera,J. PeÓn,L. Velasco,R. Miranda,A. SalmÓn,M. SalmÓn, J. Mol. Catal., 104 (1995) L5.

    Google Scholar 

  13. A. Billina,J. M. Adams,S. H. Graham, J. Chem. Soc. Chem. Commun., 1003 (1980).

  14. J. M. Adams,D. E. Clement,S. H. Graham, Clay Miner., 30 (1982) 129.

    Google Scholar 

  15. M. SalmÓn,M. PÉrez-Luna,C. Lopez-Franco,E. HernÁndez,R. A. Alvarez-RamÍrez,A. Lopez-Ortega,J. M. Dominguez, J. Molec. Catal., A122 (1997) 169.

    Google Scholar 

  16. A. Blazek, Thermal Analysis, Van Rostrand Reinhold Company, London, 1973.

    Google Scholar 

  17. C. R. Mackenzie, The Differential Thermal Investigation of Clays, Alden Press Oxford, Ltd., London, 1966.

    Google Scholar 

  18. W. N. Delgass,R. L. Garten,M. boudart, J. Phys. Chem., 73 (1969) 2970.

    Google Scholar 

  19. R. M. Barrer, FRS Zeolites and Clay Minerals as Sorbents and Molecular Sieves, Academic Press, London, New York, San Francisco, 1978.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ruiz, O.L. Characterization of a few Mexican clays. Journal of Radioanalytical and Nuclear Chemistry 250, 165–168 (2001). https://doi.org/10.1023/A:1013207719042

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1013207719042

Keywords

Navigation