Skip to main content
Log in

Effect of composition and thermal cycling on the adhesion strength of Sn-Zn-Al solder hot-dipped on Cu substrate

  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

Reliability losses in many electronic systems were identified with the failure of solder joints rather than device malfunctions. The adhesion strength is an important factor for assessing the reliability of the solder joints. In this work, a pull-off test was used to investigate the adhesion strength at the interface of the (100 − x)Sn-x(5Al-Zn) lead-free solders on Cu substrate as-soldered and after thermal cycling, respectively. For the (100 − x)Sn-x(5Al-Zn) solders with the x value increased up to 40 wt%, the adhesion strength decreased from 11.8 ± 1.5 to 3.3 ± 0.9 MPa. After thermal cycling (−20–120°C) for 40 cycles, the adhesion strength of 95Sn-5(5Al-Zn) and 91Sn-9(5Al-Zn) solders decreased from 11.2 ± 1.7 to 8.2 ± 1.3, 7.6 ± 0.7 to 5.0 ± 0.8 MPa, respectively. However, the adhesion strength for the solders of 80Sn-20(5Al-Zn), 70Sn-30(5Al-Zn) and 60Sn-40(5Al-Zn) increased from 5.7 ± 1.7 to 13.3 ± 1.9 MPa, 4.8 ± 2.0 to 12.2 ± 1.8 MPa, and 3.3 ± 1.5 to 16.2 ± 1.2 MPa, respectively. The formation of intermetallic compound (IMC) is proposed for the enhancement of the strength after thermal cycling in this study.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. J. H. LAU, “Chip on Board Technologies for Multichip Modules” (International Thomson Publishing Company, New York, 1994) chap. 1.

    Google Scholar 

  2. M. PECHT, “Handbook of Electronic Package Design” (Marcel Decker, New York, 1991) chap. 1.

    Google Scholar 

  3. D. R. FREAR, D. GRIVAS and J. W. MORRIS, J. Electron. Mater. 17(2) (1988) 171.

    Google Scholar 

  4. C. S. CHANG, A. OSCILOWSKI and R. BRACKAN, IEEE Circuits and Devices Magazine 14(2) (1998) 45.

    Google Scholar 

  5. D. R. FREAR, W. B. JONES and K. R. KINSMAN, in “Solder Mechanics,” 1st ed. (Santa Fe, New Maxico, 1990) p. 206.

  6. R. YENAWINE, M. WOLVERTON, A. BURKETT, B. WALLER, B. RUSSEL and D. SPRITZ, in Proc. 11th Naval Weapons Electronics Manufacturing Seminar, China Lake, CA, 1987, p. 339.

  7. Y. KARIYA and M. OTSUKA, J. Electron. Mater. 27(7) (1998) 866.

    Google Scholar 

  8. S. P. YU, M. H. HON, H. C. WANG and M. C. WANG, J. Miner. Metals and Mater. (JOM) 52(6) (2000) 38.

    Google Scholar 

  9. S. P. YU, M. C. WANG and M. H. HON, J. Electron. Mater. 29 (2000) 237.

    Google Scholar 

  10. S. P. YU, M. H. HON and M. C. WANG, J. Mater. Res. 16(1) (2001) 76.

    Google Scholar 

  11. S. P. YU, C. L. LIAO, M. H. HON and M. C. WANG, J. Mater. Sci. 35 (2000) 4217.

    Google Scholar 

  12. S. P. YU, S. J. LIN, M. H. HON and M. C. WANG, J.M.S.-Mater. in Electron. 11 (2000) 461.

    Google Scholar 

  13. T. TAKEMOTO, A. MATSUNAWA and M. TAKAHASHI, J. Mater. Sci. 32 (1997) 4077.

    Google Scholar 

  14. T. E. WONG, L. A. KACHATORIAN and B. D. TIERNEY, Trans. of ASME, J. Electron. Packaging 119 (1997) 171.

    Google Scholar 

  15. D. R. LIU and Y. H. PAO, J. Electron. Mater. 26(9) (1997) 1058.

    Google Scholar 

  16. C. G. SCHMIDT, J. W. SIMONS, C. H. KANAZAWA and D. C. ERLICH, IEEE Trans. on Components, Packaging, and Manufacturing Technology A 18 (1995) 611.

    Google Scholar 

  17. A. R. SYED, Trans. of ASME, J. Electron. Packaging 117 (1995) 116.

    Google Scholar 

  18. S. M. LEE and K. W. LEE, Jpn. J. Appl. Phys. 35 (1996) L1515.

    Google Scholar 

  19. R. G. ROSS, JR. and L. C. WEN, Trans. of ASME, J. Electron. Packaging 116 (1994) 69.

    Google Scholar 

  20. G. W. C. KAYE and T. H. LABY, “Tables of Physical and Chemical Constants and Some Mathematical Functions,” 13th ed. (Butterworth & Co. Ltd., 1966) p. 55. Received 27 June 2000 and accepted 3 August 2001 190

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Yu, SP., Wang, HC., Wang, MC. et al. Effect of composition and thermal cycling on the adhesion strength of Sn-Zn-Al solder hot-dipped on Cu substrate. Journal of Materials Science 37, 185–190 (2002). https://doi.org/10.1023/A:1013191101899

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1013191101899

Keywords

Navigation