Abstract
A new four-parameter corresponding-states method is presented to correlate the generalized volumetric behavior of polar and nonpolar working fluids. It is different from other corresponding-states methods in that the acentric factor is not used, instead the normal boiling temperature and critical compressibility factor are introduced as basic parameters. Comparison between experimental and calculated volumetric properties shows that highly accurate results are obtained by the new method for 18 polar and nonpolar working fluids with 3900 experimental data. The overall average absolute error for all of the fluids studied is about 0.8%.
Similar content being viewed by others
REFERENCES
Z. S. Chen, W. L. Cheng, and P. Hu, J. Eng. Thermophys. 22:19 (2001) [in Chinese].
Z. S. Chen and T. Ito, Proc. 5th Asia Thermophys. Prop. Conf., Seoul (1998), p. 321.
Z. S. Chen, and T. Ito, Proc. 5th Asia Thermophys. Prop. Conf., Seoul (1998), p. 519.
K. S. Pitzer, D. Z. Lippmann, R. F. Curl, C. M. Huggins, and D. E. Petersen, J. Am. Chem. Soc. 77:3433 (1955).
B. I. Lee and M. G. Kesler, AIChE J. 21:510 (1975).
G. Z. Wu and L. I. Stiel, AIChE J. 31:1632 (1985).
W. V. Wilding and R. L. Rowley, Int. J. Thermophys. 7:525 (1986).
G. Scalabrin, S. D. Santo, and M. Grigiante, Proc. 5th Asia Thermophys. Prop. Conf., Seoul (1998), p. 325.
K. Park, R. E. Sonntag, and C. Borgnakke, Int. J. Energy Res. 20:811 (1996).
T. Ito, R. Akasaka, T. Iwamoto, Y. Kato, T. Kuroki, T. Shigechi, Y. Takata, H. Tanigawa, H. Taniguchi, T. Hamatake, T. Fujita, T. Hoda, T. Masuoka, M. Miyamoto, S. Momoki, Y. Yasuda, T. Yamaguchi, H. Yamashita, and K. Yoshioka, A Program Package for Thermophysical Properties of Fluids, Version 11.1 (1999).
Japan Soc. Mech. Eng., 1980 SI JSME Steam Tables (1981).
K. Bühner, G. Maurer, and E. Bender, Cryogenics 21:157 (1981).
V. V. Sychev, A. A. Vasserman, A. D. Kozlov, G. A. Spiridonov, and V. A. Tsymarny, Thermodynamic Properties of Oxygen, National Standard Reference Data of the USSR: A Series of Property Tables, Vol. 5 (Hemisphere, New York, 1987).
R. Tillner-Roth and H. D. Baehr, J. Chem. Thermodyn. 24:413 (1992).
M. H. William, J. Chem. Eng. Data 28:367 (1983).
D. N. Giovanni, G. Giuliano, and P. Fabio, J. Chem. Eng. Data 44:696 (1999).
S. J. Boyes and L. A. Weber, Int. J. Thermophys. 15:443 (1994).
B. Walter, K. Gunther, and W. Rolf, J. Chem. Eng. Data 41:476 (1996).
Y. C. Hou and J. J. Martin, AIChE J. 5:125 (1959).
G. Handel, R. Kleinrahm, and W. Wagner, J. Chem. Thermodyn. 24:697 (1992).
A. Caustevo and S. Iglesias, J. Chem. Eng. Data 40:1151 (1995).
C.-C. Piao, H. Sato, and K. Watanabe, J. Chem. Eng. Data 36:398 (1991).
R. G. Rubio, J. C. G. Calado, P. Clancy, and W. N. Streett, J. Phys. Chem. 89:4637 (1985).
J. M. Martin, F. S. Richard, and N. S. Paul, J. Chem. Eng. Data, 23:113 (1978).
M. Prasad, J. Chem. Eng. Data 26:361 (1981).
M. Prasad and A. P. Kudchadker, J. Chem. Eng. Data 23:190 (1978).
Y. Maezawa, H. Sato, and K. Watanabe, J. Chem. Eng. Data 36:151 (1991).
Y. Maezawa, H. Sato, and K. Watanabe, J. Chem. Eng. Data 36:148 (1991).
N. Yada, T. Kumatsu, H. Sato, and K. Watanabe, J. Chem. Eng. Data 36:12 (1991).
L. A. Weber and D. R. Defibaugh, J. Chem. Eng. Data 41:1477 (1996).
H.L. Zhang, H. Sato, and K. Watanabe, J. Chem. Eng. Data 40:887 (1995).
H. Hou, J. C. Holste, B. E. Gammon, and K. N. Marsh, Int. J. Refrig. 15:365 (1992).
C.-C Piao, H. Sato, and K. Watanabe, ASHRAE Trans. 96: 132 (1990), Part 1.
D. P. Wilson and R. S. Basu, ASHRAE Trans. 94:2095 (1988), Part 2.
N. Pieperbeck, R. Kleinrahm, W. Wagner, and M. Jaeschke, J. Chem. Thermodyn. 23:175 (1991).
R. Kleinrahm, W. Duschek, and W. Wagner, J. Chem. Thermodyn. 20:621 (1988).
G. Handel, R. Kleinrahm, and W. Wagner, J. Chem. Thermodyn. 24: 685 (1992).
D. R. Defibaugh, K. A. Gillis, M. R. Moldover, J. W. Schmidt, and L. A. Weber, Int. J. Refrig. 19:285 (1996).
C. C. Hsu and J. J. Mcketta, J. Chem. Eng. Data 9:45 (1964).
B. Platzer, A. Polt, and G. Maurer, Thermophysical Properties of Refrigerants (Springer-Verlag, New York, 1990).
Jpn. Assoc. Refrig., Thermophysical Properties of Refrigerants (R22, Chlorodifluoromethane) (1975)
S. Angus and K. M. de Reuck, International Thermodynamic Table of the Fluid State-5 Methane, Vol. 5 (IUPAC, 1976).
R. Tillner-Roth, J. Li, A. Yokozeki, H. Sato, and K. Watanabe, Thermodynamic Properties of Pure and Blended Hydrofluorocarbon (HFC) Refrigerants (JSRAE, Tokyo, 1997).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Cheng, W.L., Chen, Z.S., Hu, P. et al. A New Generalized Four-Parameter Corresponding-States Method for Predicting Volumetric Behavior of Working Fluids. International Journal of Thermophysics 22, 1769–1779 (2001). https://doi.org/10.1023/A:1013143101294
Issue Date:
DOI: https://doi.org/10.1023/A:1013143101294