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Ternary Excess Molar Enthalpies of Alcohols with Methyl t-Butyl Ether at T=298.15 K

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Abstract

Ternary excess molar enthalpies H E m at 298.15 K and atmospheric pressure measured in a flow microcalorimeter are reported for the methanol+2-propanol+methyl t-butyl ether (MTBE) and ethanol+1-propanol+MTBE systems. The ternary results have been correlated by means of a polynomial equation and used to construct constant excess enthalpy contours. Furthermore, the results have been compared with those calculated from a UNIQUAC associated-solution model taking into account molecular association of alcohols and solvation between unlike alcohols and alcohols with MTBE using only binary information.

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Authors and Affiliations

  1. Department of Chemistry and Chemical Engineering, Division of Physical Sciences, Kanazawa University, 40-20 Kodatsuno 2-chome, Kanazawa, Ishikawa, 920-8667, Japan

    K. Tamura, M. M. H. Bhuiyan & T. Yamada

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  1. K. Tamura
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  2. M. M. H. Bhuiyan
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  3. T. Yamada
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Correspondence to K. Tamura.

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Tamura, K., Bhuiyan, M.M.H. & Yamada, T. Ternary Excess Molar Enthalpies of Alcohols with Methyl t-Butyl Ether at T=298.15 K. International Journal of Thermophysics 22, 1739–1753 (2001). https://doi.org/10.1023/A:1013139000385

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  • DOI: https://doi.org/10.1023/A:1013139000385

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