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Ionic Mobility, Phase Transitions, and Electric Conductivity in Ammonium Tetrafluoroantimonate and Heptafluorodiantimonate(III)

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Abstract

The dynamics of the fluoride and proton sublattices and the electrophysical properties of NH4SbF4 (I) and NH4Sb2F7 (II) in the temperature range 210-435 K were studied by 19F and 1H NMR and impedance spectroscopy. Types of ionic motion were determined and their activation energies were estimated. The structural phase transitions in I and II form the high-temperature modifications β-NH4SbF4 and β-NH4Sb2F7, having high ionic (superionic) conductivity in the range 425-435 K (σ∼1.9-1.5×10-3 S/cm).

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Authors and Affiliations

  1. Far East Branch, Russian Academy of Sciences, Institute of Chemistry, Vladivostok

    V. Ya. Kavun, V. I. Sergienko, L. A. Zemnukhova, T. A. Kaidalova & E. B. Merkulov

  2. Russian Academy of Sciences, A. V. Shubnikov Institute of Crystallography, Moscow

    N. I. Sorokin

Authors
  1. V. Ya. Kavun
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  2. V. I. Sergienko
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  3. N. I. Sorokin
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  4. L. A. Zemnukhova
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  5. T. A. Kaidalova
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  6. E. B. Merkulov
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Kavun, V.Y., Sergienko, V.I., Sorokin, N.I. et al. Ionic Mobility, Phase Transitions, and Electric Conductivity in Ammonium Tetrafluoroantimonate and Heptafluorodiantimonate(III). Journal of Structural Chemistry 42, 570–577 (2001). https://doi.org/10.1023/A:1013133607775

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  • DOI: https://doi.org/10.1023/A:1013133607775

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