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Studies of Dehydration Process for Isostructural Series of Lanthanide(III) 2,6-dihydroxybenzoates

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Abstract

Dehydration kinetics of lanthanide 2,6-dihydroxybenzoates has been studied by thermogravimetry using the model-fitting method of calculation. Several kinetic models gavea good representation of the measured thermogravimetric (TG) curves but the calculation method allowed to propose the most probable dehydration mechanism. The activation energies of dehydration for isostructural 2,6-dihydroxybenzoates of lanthanides are similar for a given kinetic model. A change in the heating rate did not alter the dehydration mechanism. A linear correlation between the activation energy and the heating rate was observed for the systems studied.

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Authors and Affiliations

  1. Department of General Chemistry, Maria Curie-Skłodowska University, Maria Curie Skłodowska Sq. 2, 20-031, Lublin, Poland

    M. Sikorska-Iwan, Z. Rzączyńska & A. Kula

  2. Department of Chemistry, Kent State University, Kent, Ohio, 44242-0001, USA

    M. Jaroniec

Authors
  1. M. Sikorska-Iwan
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  2. Z. Rzączyńska
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  3. A. Kula
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  4. M. Jaroniec
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Sikorska-Iwan, M., Rzączyńska, Z., Kula, A. et al. Studies of Dehydration Process for Isostructural Series of Lanthanide(III) 2,6-dihydroxybenzoates. Journal of Thermal Analysis and Calorimetry 66, 841–849 (2001). https://doi.org/10.1023/A:1013104408182

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