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Recombination Chemiluminescence in Photoirradiation of Epoxy Acrylate Polymer Compositions and Its Use for Monitoring of the Network Structure Development

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Abstract

Photoinduced recombination chemiluminescence was applied for monitoring of the network structure formation under UV exposure of films prepared by esterification with acrylic acid of oligomers such as UP-612, ED-16, and Oksilin commercial epoxy resins. The chemiluminescence decay was described in terms of the fractal kinetics model. The spectral dimension parameter, apparent luminescence activation energies, and glass transition temperatures of the polymers were calculated.

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Authors and Affiliations

  1. Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, Ufa, Bashkortostan, Russia

    O. L. Kramer, E. M. Battalov, A. I. Voloshin & Yu. A. Prochukhan

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  1. O. L. Kramer
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  2. E. M. Battalov
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  3. A. I. Voloshin
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  4. Yu. A. Prochukhan
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Kramer, O.L., Battalov, E.M., Voloshin, A.I. et al. Recombination Chemiluminescence in Photoirradiation of Epoxy Acrylate Polymer Compositions and Its Use for Monitoring of the Network Structure Development. Russian Journal of Applied Chemistry 74, 1190–1193 (2001). https://doi.org/10.1023/A:1013087422351

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