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Crystal structure and excimer fluorescence of dibenzoylmethanatoboron difluoride

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Abstract

Fluorescence properties of dilute and concentrated solutions of dibenzoylmethanatoboron difluoride and its crystals were studied. Excimers are formed in concentrated solutions and crystals of dibenzoylmethanatoboron difluoride. The crystal structure of dibenzoylmethanatoboron difluoride was determined by X-ray diffraction analysis. It was found that the molecules of dibenzoylmethanatoboron difluoride are coplanar with an interplanar distance of 3.6 Å.

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Authors and Affiliations

  1. Institute of Chemistry, Far-Eastern Branch of the Russian Academy of Sciences, 159 prosp. 100-letiya Vladivostoka, 690022, Vladivostok, Russian Federation

    A. G. Mirochnik, B. V. Bukvetskii, E. V. Gukhman, P. A. Zhikhareva & V. E. Karasev

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  1. A. G. Mirochnik
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  2. B. V. Bukvetskii
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  3. E. V. Gukhman
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  4. P. A. Zhikhareva
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  5. V. E. Karasev
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Mirochnik, A.G., Bukvetskii, B.V., Gukhman, E.V. et al. Crystal structure and excimer fluorescence of dibenzoylmethanatoboron difluoride. Russian Chemical Bulletin 50, 1612–1615 (2001). https://doi.org/10.1023/A:1013086518794

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