Abstract
The formation enthalpies (ΔH f°) of 12 organosulfur radicals (R·) were determined for the first time from the published values of dissociation energies of R—X bonds.
Similar content being viewed by others
References
Yu. D. Orlov, V. O. Lavrov, and Yu. A. Lebedev, Izv. Akad. Nauk, Ser. Khim., 2001, 923 [Russ. Chem. Bull., Int. Ed., 2001, 50, 963].
Yu. D. Orlov, R. Kh. Zaripov, and Yu. A. Lebedev, Izv. Akad. Nauk, Ser. Khim., 1998, 643 [Russ. Chem. Bull., 1998, 47, 621 (Engl. Transl.)].
Yu. D. Orlov, R. Kh. Zaripov, and Yu. A. Lebedev, Izv. Akad. Nauk, Ser. Khim., 1998, 637 [Russ. Chem. Bull., 1998, 47, 615 (Engl. Transl.)].
Yu. D. Orlov and Yu. A. Lebedev, Izv. Akad. Nauk, Ser. Khim., 1999, 286 [Russ. Chem. Bull., 1999, 48, 285 (Engl. Transl.)].
Yu. D. Orlov, A. A. Tomilin, and Yu. A. Lebedev, Zh. Fiz. Khim., 2000, 74, 1058 [Russ. J. Phys. Chem., 2000, 74 (Engl. Transl.)].
Handbook of Chemistry and Physics, CRC Press, Florida, 1995, 9; 1996, 9.
Yu. D. Orlov, Doct. Sci. (Chem.) Thesis, Tver State University, Tver, 1996 (in Russian).
B. K. Janousek, K. J. Reed, and J. I. Brauman, J. Am. Chem. Soc., 1980, 102, 3125.
J. B. Pedley, R. D. Naylor, and S. P. Kirby, Thermochemical Data of Organic Compounds, Chapman and Hall, London-New York, 1986.
E. T. Denisov, Zh. Fiz. Khim., 1996, 70, 260 [Russ. J. Phys. Chem., 1996, 70 (Engl. Transl.)].
F. G. Bordwell, X. Zhand, and Z.-P. Chend, J. Org. Chem., 1991, 56, 3216.
F. G. Bordwell, J. A. Harrelson, and T.-Y. Lynch, J. Org. Chem., 1990, 55, 3337.
F. G. Bordwell, J.-P. Cheng, G.-Z. Ji, A. V. Satish, and X. Zhang, J. Am. Chem. Soc., 1991, 113, 9790.
R. Sabbah and L. A. Gomez, Thermochim. Acta, 1982, 52, 285.
M. D. M. C. Ribeiro Da Silva, P. Souza, and G. Pilcher, J. Chem. Thermodyn., 1989, 21, 173.
L. A. T. Gomez and R. Sabbah, Thermochim. Acta, 1982, 57, 67.
H. M. Rosenstock, J. Dannacher, and J. F. Liebman, Radiat. Phys. Chem., 1982, 20, 7.
D. R. Stull, E. F. Westrum, and G. C. Sinke, The Chemical Thermodynamics of Organic Compounds, J. Wiley and Sons, New York, 1969.
Yu. A. Lebedev and E. A. Miroshnichenko, Thermochemistry of Organic Substance Evaporation in Thermochemistry and Equilibria of Organic Compounds, VCH Publ., New York, 1993, 2, 165.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Orlov, Y.D., Turovtsev, V.V. & Lebedev, Y.A. The determination of enthalpies of formation of organic free radicals from bond dissociation energies. 5. Organosulfur radicals. Russian Chemical Bulletin 50, 1570–1571 (2001). https://doi.org/10.1023/A:1013070115160
Issue Date:
DOI: https://doi.org/10.1023/A:1013070115160