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Coordination chemistry of macrocyclic multidentate Lewis acids. Synthesis and structures of complexes of cyclic trimeric perfluoro-o-phenylenemercury with N,N-dimethylacetamide and n-butyronitrile

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Abstract

Cyclic trimeric perfluoro-o-phenylenemercury (o-C6F4Hg)3 readily reacts with N,N-dimethylacetamide and n-butyronitrile to form the complexes {[(o-C6F4Hg)3](MeCONMe2)2} and {[(o-C6F4Hg)3](PrnCN)}, respectively. According to X-ray diffraction data, the amide ligands are located above and below the plane of the macrocycle, each being coordinated to all Hg atoms of the macrocycle through the O atom. The nitrile ligand is bound to the macrocycle through the N atom, all Hg atoms being also involved in this bonding.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    I. A. Tikhonova, F. M. Dolgushin, K. I. Tugashov, P. V. Petrovskii & V. B. Shur

  2. Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, 9 prosp. Akad. Lavrent"eva, 630090, Novosibirsk, Russian Federation

    G. G. Furin

Authors
  1. I. A. Tikhonova
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  2. F. M. Dolgushin
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  3. K. I. Tugashov
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  4. G. G. Furin
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  5. P. V. Petrovskii
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  6. V. B. Shur
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Tikhonova, I.A., Dolgushin, F.M., Tugashov, K.I. et al. Coordination chemistry of macrocyclic multidentate Lewis acids. Synthesis and structures of complexes of cyclic trimeric perfluoro-o-phenylenemercury with N,N-dimethylacetamide and n-butyronitrile. Russian Chemical Bulletin 50, 1673–1678 (2001). https://doi.org/10.1023/A:1013059207407

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