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Synthesis and structure of the polymeric cluster compound [Mn(H2O)4]3[W4S4(CN)12]·nH2O containing very large cavities

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Abstract

The compound [Mn(H2O)4]3[W4S4(CN)12]·nH2O (1) was prepared by the reaction of an aqueous solution of MnSO4 with a glycerol solution of KCs5[W4S4(CN)12]·4H2O. Complex 1 was characterized by X-ray diffraction analysis and IR spectroscopy. According to the X-ray diffraction data, the three-dimensional polymeric framework of 1 comprises only 24.2% of the unit-cell volume. The volume of the cavities per formula unit is 1664 Å3. The cavities are occupied by highly disordered water molecules.

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Lavrent"eva, 630090, Novosibirsk, Russian Federation

    V. P. Fedin, I. V. Kalinina & A. V. Virovets

  2. Institüt für Anorganishe Chemie, Universität Karlsruhe, Engesserstraße Geb. 30.45, Karlsruhe, 76128, Germany

    D. Fenske

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  1. V. P. Fedin
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  2. I. V. Kalinina
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  3. A. V. Virovets
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  4. D. Fenske
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Fedin, V.P., Kalinina, I.V., Virovets, A.V. et al. Synthesis and structure of the polymeric cluster compound [Mn(H2O)4]3[W4S4(CN)12]·nH2O containing very large cavities. Russian Chemical Bulletin 50, 1525–1528 (2001). https://doi.org/10.1023/A:1013057712434

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