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Crystal Structure of NH4NaTiF6and Internal Mobility of the Complex Anions

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Abstract

Single crystals of NH4NaTiF6are studied by X-ray diffraction analysis (automated diffractometer, MoK αradiation, graphite monochromator, sin θ/λ ≤ 1.0 Å–1, 1566 reflections with I> 3σ(I ), anisotropic least squares method to R= 0.045 and R w= 0.040). The compound belongs to the NaRbSnF6structural type. The types of internal motions of the complex ions NH4 +and TiF6 2–are determined in the temperature range 200–500 K and compared with the motion of ionic groups in (NH4)2TiF6and Na2TiF6crystals.

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Authors and Affiliations

  1. Institute of Chemistry, Far East Division, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok, 690022, Russia

    D. Yu. Popov, V. Ya. Kavun, T. F. Antokhina, A. V. Gerasimenko & V. I. Sergienko

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  1. D. Yu. Popov
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  2. V. Ya. Kavun
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  3. T. F. Antokhina
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  4. A. V. Gerasimenko
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  5. V. I. Sergienko
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Popov, D.Y., Kavun, V.Y., Antokhina, T.F. et al. Crystal Structure of NH4NaTiF6and Internal Mobility of the Complex Anions. Russian Journal of Coordination Chemistry 27, 831–834 (2001). https://doi.org/10.1023/A:1013031126720

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