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Intramolecular Mobility in the Complexes 2SbCl3· p-C6H4(CH3)2and SbCl3· C6H5COCH3according to 35Cl NQR Data

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Abstract

Temperature dependences of the 35Cl and 121Sb spin-lattice relaxation time τ1in antimony trichloride complexes with p-xylene and acetophenone were studied using NQR spectroscopy. The activation energies of the retarded motion (similar to that discovered in some vπ complexes of SbCl3) of chlorine atoms were determined from the 35Cl τ1(T) function. New data on the shape of the 121Sb τ1(T) function are discussed.

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  1. Perm State University, ul. Bukireva 15, Perm, 614600, Russia

    I. A. Kyuntsel' & V. A. Mokeeva

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  1. I. A. Kyuntsel'
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  2. V. A. Mokeeva
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Kyuntsel', I.A., Mokeeva, V.A. Intramolecular Mobility in the Complexes 2SbCl3· p-C6H4(CH3)2and SbCl3· C6H5COCH3according to 35Cl NQR Data. Russian Journal of Coordination Chemistry 27, 835–837 (2001). https://doi.org/10.1023/A:1013004810790

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