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2-Polyfluoroalkylchromones. 9. Synthesis and structures of 5-(2-hydroxyaryl)-7-polyfluoroalkyl-1,4,8-triazabicyclo[5.3.0]dec-4-enes

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Russian Chemical Bulletin Aims and scope

Abstract

2-Polyfluoroalkylchromones reacted with diethylenetriamine at ∼20 °C to form the corresponding 1,4,8-triazabicyclo[5.3.0]dec-4-ene derivatives. The crystal structures of 5-(2-hydroxyphenyl)-7-trifluoromethyl-1,4,8-triazabicyclo[5.3.0]dec-4-ene and 1-(2-aminoethyl)-7-(2-hydroxy-5-methoxyphenyl)-5-(1,1,2,2-tetrafluoroethyl)-2,3-dihydro-1H-1,4-diazepine were established by X-ray diffraction analysis.

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Authors and Affiliations

  1. A. M. Gorky Ural State University, 51 prosp. Lenina, 620083, Ekaterinburg, Russian Federation

    V. Ya. Sosnovskikh & I. I. Vorontsov

  2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    V. A. Kutsenko

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  1. V. Ya. Sosnovskikh
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  2. I. I. Vorontsov
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  3. V. A. Kutsenko
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Sosnovskikh, V.Y., Vorontsov, I.I. & Kutsenko, V.A. 2-Polyfluoroalkylchromones. 9. Synthesis and structures of 5-(2-hydroxyaryl)-7-polyfluoroalkyl-1,4,8-triazabicyclo[5.3.0]dec-4-enes. Russian Chemical Bulletin 50, 1430–1438 (2001). https://doi.org/10.1023/A:1012793208952

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