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Kinetics of Leaching of Nickel Compounds from Spent Electrodes of Nickel-Iron Batteries in Ammonia Solutions

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Abstract

The extent of nickel recovery from spent electrodes of nickel-iron batteries in ammonia solutions was studied in relation to time and leaching temperature. The optimal time and the temperature at which the extent of nickel recovery in leaching solutions containing ammonium salts is the highest were determined and the dependence of the process efficiency on the anionic composition of the solution was analyzed. The apparent activation energies of nickel leaching from the active mass preliminarily extracted from lamellas are calculated, and the adequacy to the actual process of the model of leaching controlled by external diffusion is assessed.

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REFERENCES

  1. Sittig, M., Metal and Inorganic Waste Reclaiming Encyclopedia, New York: Park Ridge, 1980.

    Google Scholar 

  2. Khudyakov, I.F., Doroshkevich, A.P., and Karelov, S.V., Metallurgiya vtorichnykh tyazhelykh tsvetnykh metallov (Metallurgy of Secondary Heavy Non-Ferrous Metals), Moscow: Metallurgiya, 1987.

    Google Scholar 

  3. Zhang, P., Yokoyama, T., Itabashi, O., et al., Hydrometallurgy, 1998, vol. 50, no. 1, pp. 61–75.

    Google Scholar 

  4. Nogueira, C.A. and Delmas, F., Hydrometallurgy, 1999, vol. 52, no. 3, pp. 267–287.

    Google Scholar 

  5. Borbat, V.F. and Leshch, I.Yu., Novye protsessy v metallurgii nikelya i kobal'ta (New Processes in Metallurgy of Nickel and Cobalt), Moscow: Metallurgiya, 1976.

    Google Scholar 

  6. Khudyakov, I.F., Tikhonov, A.M., Deev, D.I., and Naboichenko, S.S, Metallurgiya medi, nikelya i kobal'ta (Metallurgy of Copper, Nickel, and Cobalt), Moscow: Metallurgiya, 1977, vol. 2.

    Google Scholar 

  7. Bukin, V.I., Reznik, A.M., Vasil'chenko, S.V., and Granat, N.A., Present State of, and Prospects for Use of Extraction in Ammonia Processing of Nickel-and Cobalt-Containing Raw Materials, Obzor. Inform. TsNIIEI TsM, Ser. Proizv. Tyazh. Tsvetn. Met., 1983, issue 3.

  8. Demidov, A.I. and Krasovitskaya, O.A., Zh. Prikl. Khim., 2000, vol. 73, no. 10, pp. 1656–1660.

    Google Scholar 

  9. Bretsznajder, S., Kawecki, W., Zeyko, G., and Marcinkowski, R., Podstawy ogolnetechnologii chemicznej, Warsaw: Naukowo-Technicznej, 1973.

    Google Scholar 

  10. Habashi, F., Principles of Extractive Metallurgy, New York: Gordon and Breach, 1969.

    Google Scholar 

  11. Zelikman, A.N., Vol'dman, G.M., and Belyaevskaya, L.V., Teoriya gidrometallurgicheskikh protsessov, Moscow: Metallurgiya, 1983.

    Google Scholar 

  12. Beloglazov, I.N., Morachevskii, A.G., and Zhmarin, E.E., Kineticheskie zakonomernosti protsessov rastvoreniya i vyshchelachivaniya (Kinetics of Dissolution and Leaching), Moscow: Ruda i Metally, 2000.

    Google Scholar 

  13. Bulanov, V.Ya., Vatolin, N.A., Zalazinskii, G.G., and Volkova, P.I., Gidrometallurgiya zheleznykh poroshkov (Hydrometallurgy of Iron Powder), Moscow: Nauka, 1984.

    Google Scholar 

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Demidov, A.I., Krasovitskaya, O.A. Kinetics of Leaching of Nickel Compounds from Spent Electrodes of Nickel-Iron Batteries in Ammonia Solutions. Russian Journal of Applied Chemistry 74, 737–741 (2001). https://doi.org/10.1023/A:1012776513996

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