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Untypical Surface Properties of the System Caprylic Acid + n-Propyl Acetate

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Abstract

The surface tensions σ of nonaqueous solutions of n-propyl acetate in caprylic (n-octanoic) acid were measured between 273 and 303 K using the Wilhelmy plate method. Complicated concentration dependences were obtained, different from any previously reported. In addition, independent volumetric and acoustic (sound velocity and absorption) methods were applied. The results are interpreted in terms of formation of weak complexes in the bulk as well as at the surface.

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Authors and Affiliations

  1. Faculty of Chemistry, University of Wrocław, F. Joliot-Curie, 14, 50-383, Wrocław, Poland

    Jacek Gliński & Jan Przybylski

  2. University of Mons, Mons, Belgium

    Guy Chavepeyer & Jean-Karl Platten

Authors
  1. Jacek Gliński
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  2. Jan Przybylski
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  3. Guy Chavepeyer
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  4. Jean-Karl Platten
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Gliński, J., Przybylski, J., Chavepeyer, G. et al. Untypical Surface Properties of the System Caprylic Acid + n-Propyl Acetate. Journal of Solution Chemistry 30, 925–936 (2001). https://doi.org/10.1023/A:1012775715174

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  • DOI: https://doi.org/10.1023/A:1012775715174

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