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Cluster Model of Aggregation of Epoxy-DPP Oligomers in Solutions. Structure of Coatings Based on Epoxy and Epoxy-Phenol Resins

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Abstract

The IR MATIR spectra in the 1535-1680 cm-1 range were studied for epoxy-DPP resins (M N = 1650-3400) in coatings on germanium substrate obtained from oligomer solutions in methylene chloride and Cellosolve with the concentration c = 10-50%. The concentration dependences of the relative viscosity of narrow-MWD fractions of epoxy oligomers (M N = 1500-5300) in chloroform and Cellosolve solutions were studied. The structure of the network of cross-linked polymers based on epoxy (M N = 2100-3400) and phenol-formaldehyde (M N = 860) resins was studied by the electron-microscopic silver chloride decoration method. Based on the cluster lattice model, the optimal molecular weight and the concentration regimes were determined for epoxy oligomers in the lacquer composition for can protection.

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REFERENCES

  1. Kurmakova, I.N., Novikov, N.A., Mozoleva, A.P., et al., Lakokras. Mater. Ikh Primen., 1985, no. 5, pp. 11-13.

  2. Lakokrasochnye materialy dlya zachshity konservnoi tary (Paint and Varnish Materials for Can Protection), Lyalyushko, S.M., Ed., Moscow: NIITEKhIM, 1981.

    Google Scholar 

  3. Chernin, I.Z., Smekhov, F.M., and Zherdyaev, Yu.M., Epoksidnye polimery i kompozitsii (Epoxy Polymers and Compositions), Moscow: Khimiya, 1982.

    Google Scholar 

  4. Markevich, M.A., Structural and Kinetic Aspects of the Processes of Formation of Epoxy--DPP Oligomers and Three-Dimensional Polymers Thereof, Doctoral Dissertation, Chernogolovka, 1986.

  5. Markevich, M.A., Kuzaev, A.I., Shashkin, D.P., et al., Vysokomol. Soedin., Ser. A, 1985, vol. 27, no. 3, pp. 1000-1007.

    Google Scholar 

  6. Harrick, N.J., Internal Reflection Spectroscopy, New York: Interscience, 1964.

    Google Scholar 

  7. Krasovskii, A.N., Kharlampiev, A.A., and Krasheninnikov, V.A., Vysokomol. Soedin., Ser. A, 1997, vol. 39, no. 2, pp. 250-258.

    Google Scholar 

  8. Saidov, G.V., Spektroskopiya vnutri-i mezhmolekulyarnykh vzaimodeistvii (Spectroscopy of Intra-and Intermolecular Interactions), Bakhshiev, N.G., Ed., Leningrad: Leningr. Gos. Univ., 1985, issue 4, pp. 5-14.

    Google Scholar 

  9. Vuks, M.F., Elektricheskie i opticheskie svoistva molekul i kondensirovannykh sred (Electrical and Optical Properties of Molecules and Condensed Media), Leningrad: Leningr. Gos. Univ., 1984.

    Google Scholar 

  10. Krasovskii, A.N., Kharlampiev, A.A., and Polyakov, D.N., Zh. Prikl. Khim., 1994, vol. 67, no. 3, pp. 455-463.

    Google Scholar 

  11. Kharlampiev, A.A., Spectra of Optical Constants and Structure of Boundary (Surface) Layers of Polymers for Photography and Recording Media, Cand. Sci. Dissertation, St. Petersburg, 1999.

  12. Krasovskii, A.N., Polyakov, D.N., Baranov, V.G., and Mnatsakanov, S.S., Vysokomol. Soedin., Ser. A, 1991, vol.33, no. 6, pp. 1221-1227.

    Google Scholar 

  13. Feder, J., Fractals, New York: Plenum, 1988.

    Google Scholar 

  14. Krasovskii, A.N., Nikolaev, B.P., Shlyakov, A.M., and Mnatsakanov, S.S., Kolloidn. Zh., 1994, vol. 56, no. 3, pp. 371-375.

    Google Scholar 

  15. Grosberg, A.Yu. and Khokhlov, A.R., Statisticheskaya fizika makromolekul (Statistical Physics of Macromolecules), Moscow: Nauka, 1989.

  16. Novikov, D.V. and Varlamov, A.V., Kolloidn. Zh., 1997, vol. 59, no. 3, pp. 355-359.

    Google Scholar 

  17. Markevich, M.A., Vladimirov, L.V., Prut, E.V., and Enikolopyan, N.S., Mekh. Kompozits. Mater., 1985, no. 1, pp. 25-28.

  18. Tsvetkov, V.N., Eskin, V.E., and Frenkel', S.Ya., Struktura makromolekul v rastvorakh (Structure of Macromolecules in Solutions), Moscow: Nauka, 1964.

    Google Scholar 

  19. Gorshkov, A.V., Verenich, S.S., Evreinov, V.V., and Entelis, S.G., Chromatographia, 1988, vol. 26, pp. 338-342.

    Google Scholar 

  20. Al'perovich, L.I., Metod dispersionnykh sootnoshenii i ego primenenie dlya opredeleniya opticheskikh kharakteristik (Method of Dispersion Relations and Its Application for Determination of Optical Characteristics), Dushanbe: Irfon, 1973.

    Google Scholar 

  21. Krasovskii, A.N. and Novikov, D.V., Zh. Prikl. Khim., 1999, vol. 72, no. 9, pp. 1518-1527.

    Google Scholar 

  22. Novikov, D.V., Krasovskii, A.N., Andreeva, A.I., and Basov, S.V., Kolloidn. Zh., 1999, vol. 61, no. 2, pp. 240-245.

    Google Scholar 

  23. Novikov, D.V. and Varlamov, A.V., Poverkhnost', 1992, no. 6, pp. 117-121.

  24. El'yashevich, A.M., Preprint of Report, Soveshchanie “Problemy teorii polimerov v tverdoi faze” (Meet. “Problems of the Theory of Polymers in Solid Phase”), Chernogolovka: Inst. Khim. Fiz. Akad. Nauk SSSR, 1985.

    Google Scholar 

  25. Ziman, J.M., Models of Disorder: The Theoretical Physics of Homogeneously Disordered Systems, Cambridge: Cambridge Univ. Press, 1979.

    Google Scholar 

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Authors and Affiliations

  1. Russia Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg State University of Motion Pictures and Television, St. Petersburg, St. Petersburg, Russia

    A. N. Krasovskii, D. V. Novikov, V. A. Krasheninnikov, A. B. Plodistyi, A. A. Kharlampiev & K. A. Bespalyi

  2. Pigment Research and Production Association, Joint-Stock Company, St. Petersburg, Russia

    A. N. Krasovskii, D. V. Novikov, V. A. Krasheninnikov, A. B. Plodistyi, A. A. Kharlampiev & K. A. Bespalyi

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  1. A. N. Krasovskii
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  2. D. V. Novikov
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  3. V. A. Krasheninnikov
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  4. A. B. Plodistyi
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  5. A. A. Kharlampiev
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  6. K. A. Bespalyi
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Krasovskii, A.N., Novikov, D.V., Krasheninnikov, V.A. et al. Cluster Model of Aggregation of Epoxy-DPP Oligomers in Solutions. Structure of Coatings Based on Epoxy and Epoxy-Phenol Resins. Russian Journal of Applied Chemistry 74, 131–141 (2001). https://doi.org/10.1023/A:1012772706475

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