Skip to main content
SpringerLink
Log in

Comparative Analysis of the Methods for Calculating the Viscosity of Binary Nonelectrolyte Mixtures

  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

The results of calculating the viscosity of binary nonelectrolyte systems by methods obviating fitting parameters were compared. A method was proposed for calculating the viscosity of n-alkanol-n-alkane solutions with account of the molecular association by the free-volume theory accurately to within 7.9%.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Krasovskii, A.N., Kharlampiev, A.A., and Tkach, V.P., Zh. Prikl. Khim., 1997, vol. 70, no. 7, pp. 1165–1174.

    Google Scholar 

  2. Sumarokova, G.N. and Berger, E.N., Zh. Prikl. Khim., 1997, vol. 70, no. 9, pp. 1432–1442.

    Google Scholar 

  3. Stupishina, G.N. and Vershinina, V.I., Biokhimiya, 1998, vol. 63, no. 11, pp. 1503–1508.

    Google Scholar 

  4. Abramzon, A.A. and Petel'skii, M.B., Zh. Prikl. Khim., 1998, vol. 71, no. 8, pp. 1282–1285.

    Google Scholar 

  5. Afanas'ev, V.N., Efremova, L.S., and Volkova, T.V., Fizikokhimicheskie svoistva binarnykh rastvoritelei: Vodosoderzhashchie sistemy (Physicochemical Properties of Binary Solvents: Water-Containing Systems), Ivanovo, 1988, part 1.

  6. V'yugin, A.I., Zverev, V.A., and Krestov, G.A., in Termodinamika i stroenie rastvorov (Thermodynamics and Structure of Solutions), Ivanovo, 1976, issue 5, pp. 50–53.

  7. Kanti, M., Lagourette, B., Alliez, J., and Boned, C., Fluid Phase Equil., 1991, vol. 65, pp. 291–304.

    Google Scholar 

  8. Syrnikov, Yu. P., Penkina, N.V., Kiselev, M.G., and Pukhovskii, Yu. P., Zh. Fiz. Khim., 1992, vol. 66, no. 3, pp. 185–189.

    Google Scholar 

  9. Luk'yanchikova, I. A., Nikiforov, M.Yu., and Al' per, G.A., Zh. Fiz. Khim., 1998, vol. 72, no. 7, pp. 1230–1235.

    Google Scholar 

  10. Glasstone, S., Laidler, K.J., and Eyring, H., The Theory of Rate Processes. The Kinetics of Chemical Reactions, Viscosity, Diffusion, and Electrochemical Phenomena, New York: McGraw-Hill, 1941.

    Google Scholar 

  11. Cohen, M. H. and Turnbull, D., J. Chem. Phys., 1959, vol. 31, no. 5, pp. 1164–1169.

    Google Scholar 

  12. Bloomfield, V.A. and Dewan, R.K., J. Phys. Chem., 1971, vol. 75, no. 20, pp. 3113–3119.

    Google Scholar 

  13. McAlister, R.L., Am. Inst. Chem. Eng. J., 1960, vol. 6, no. 3, pp. 427–431.

    Google Scholar 

  14. Katti, R.K. and Chaudry, M.M., J. Chem. Eng. Data, 1964, vol. 9, no. 5, pp. 442–443.

    Google Scholar 

  15. Heric, E.L., J. Chem. Eng. Data, 1966, vol. 11, no. 1, pp. 66–68.

    Google Scholar 

  16. Nikiforov, M. Yu., Al'per, G.A., and Krestov, G.A., Zh. Fiz. Khim., 1988, vol. 62, no. 6, pp. 16841686.

    Google Scholar 

  17. Lebedev, Yu. A. and Miroshnichenko, E.A., Termokhimiya paroobrazovaniya organicheskikh veshchestv: Teploty ispareniya, sublimatsii i davleniya nasyshchennogo para (Thermochemistry of Vaporization of Organic Substances: Heats of Vaporization and Sublimation and Saturated Vapor Pressure), Moscow: Nauka, 1981.

    Google Scholar 

  18. Belousov, V.P. and Morachevskii, A.G., Teploty smesheniya zhidkostei (Heats of Liquid Mixing), Leningrad: Khimiya, 1970.

    Google Scholar 

  19. Belousov, V.P., Morachevskii, A.G., and Panov, M.Yu., Teplovye svoistva rastvorov neelektrolitov (Thermal Properties of Nonelectrolyte Solutions), Leningrad: Khimiya, 1981.

    Google Scholar 

  20. Krestov, G.A., Fiziko-khimicheskie svoistva binarnykh rastvoritelei (Physicochemical Properties of Binary Solvents), Leningrad: Khimiya, 1988.

    Google Scholar 

  21. Macedo, P.B. and Litovitz, T.A., J. Chem. Phys., 1965, vol. 42, no. 2, pp. 245–256.

    Google Scholar 

  22. Erdey-Gruz, T., Transport Phenomena in Aqueous Solutions, Budapest: Akad. Kiado, 1974.

    Google Scholar 

  23. Flory, P.J., Orwoll, R.A., and Vrij, A., J. Am. Chem. Soc., 1964, vol. 86, no. 17, pp. 3507–3520.

    Google Scholar 

  24. Reid, R.G., Prausnitz, J.M., and Sherwood, T.K., The Properties of Gases and Liquids, New York: McGraw-Hill, 1977.

    Google Scholar 

  25. Petrino, P.J., Gaston-Bonhomme, Y.H., and Chevalier, J.L.E., J. Chem. Eng. Data, 1995, vol. 40, no. 1, pp. 136–140.

    Google Scholar 

  26. Aucejo, A., Cruz Burguet, M., Munoz, R., and Marques, J.L., J. Chem. Eng. Data, 1995, vol. 40, no. 1, pp. 141–147.

    Google Scholar 

  27. Heintz, A., Ber. Bunsenges. Phys. Chem., 1985, vol. 89, no. 2, pp. 172–181.

    Google Scholar 

  28. Heintz, A., Schmittecker, B., Wagner, D., and Lichtenthaler, R.N., J. Chem. Eng. Data, 1986, vol. 31, no. 4, pp. 487–492.

    Google Scholar 

  29. Wagner, D. and Heintz, A., J. Chem. Eng. Data, 1986, vol. 31, no. 4, pp. 483–487.

    Google Scholar 

  30. Bender, M. and Heintz, A., Fluid Phase Equil., 1991, vol. 67, pp. 241–257.

    Google Scholar 

  31. Franjo, C., Jimenes, E., Iglesias, T.R., et al., J. Chem. Eng. Data, 1995, vol. 40, no. 1, pp. 68–70.

    Google Scholar 

  32. Franjo, C., Menaut Consolacion, P., Jimenes, E., et al., J. Chem. Eng. Data, 1995, vol. 40, no. 4, pp. 992–994.

    Google Scholar 

  33. Treszczanowicz, A.J. and Benson, G.C., Fluid Phase Equil., 1993, vol. 89, pp. 31–56.

    Google Scholar 

  34. D'Aprano, A., Donato, I.D., and Turco Liveri, V., J. Solution Chem., 1990, vol. 19, no. 7, pp. 711–720.

    Google Scholar 

  35. Papaioannou, D. and Panayiotou, C., J. Chem. Eng. Data, 1994, vol. 39, no. 3, pp. 463–466.

    Google Scholar 

  36. Totchasov, E.D., Luk'yanchikova. I.A., Nikiforov, M.Yu., and Al'per, G.A., Vyazkost' binarnykh rastvorov neelektrolitov na osnove propanola i izopropanola (Viscosity of Binary Nonelectrolyte Solutions Based on Propanol and Isopropanol), Available from VINITI, 1998, no. 1097-V98.

  37. Totchasov, E.D., Luk'yanchikova, I.A., Nikiforov, M.Yu., and Al'per, G.A., Abstracts of Papers, VII Mezhdunarodnaya konfertentsiya “Problemy sol'-vatatsii i kompleksoobrazovaniya v rastvorakh” (VII Int. Conf. “Problems of Solvation and Complexation in Solutions”), Ivanovo, 1998, p. 64.

  38. Rappon, M. and Kaukinen, J.A., J. Mol. Liq., 1988, vol. 38, no. 2, pp. 107–133.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo, Russia

    E. D. Totchasov, M. Yu. Nikiforov, I. A. Luk'yanchikova & G. A. Al'per

Authors
  1. E. D. Totchasov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. Yu. Nikiforov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. A. Luk'yanchikova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. G. A. Al'per
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Totchasov, E.D., Nikiforov, M.Y., Luk'yanchikova, I.A. et al. Comparative Analysis of the Methods for Calculating the Viscosity of Binary Nonelectrolyte Mixtures. Russian Journal of Applied Chemistry 74, 822–829 (2001). https://doi.org/10.1023/A:1012761505335

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1012761505335

Keywords

Search

Navigation